Synthesis of carbonates directly from 1 atm CO2 and alcohols using CH2Cl2

被引：26
作者：
Yamazaki, Yusuke [1 ]
Kakuma, Kasumi [1 ]
Du, Ya [1 ]
Saito, Susumu [1 ,2 ]
机构：
[1] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[2] Nagoya Univ, Inst Adv Res, Chikusa Ku, Nagoya, Aichi 4648601, Japan
来源：
TETRAHEDRON | 2010年 / 66卷 / 51期
关键词：
1 atm Carbon dioxide; Dichloromethane; Carbonate; Alcohol; Cesium carbonate; PRIMARY ALIPHATIC-AMINES; DIMETHYL CARBONATE; CATALYZED SYNTHESIS; CARBOXYLIC-ACIDS; PROPYLENE CARBONATE; NAY FAUJASITE; DIOXIDE; ALLYL; HYDROGENATION; PALLADIUM;
D O I：
10.1016/j.tet.2010.10.051
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We introduced here a new one-pot, general procedure for the preparation of dialkyl carbonates from alcohols in a straightforward fashion under 1 atm pressure of CO2 using Cs2CO3 and CH2Cl2 as key reagents. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：9675 / 9680
页数：6
相关论文
共 78 条
  • [31] HOMOGENEOUS CATALYTIC-HYDROGENATION OF SUPERCRITICAL CARBON-DIOXIDE
    JESSOP, PG
    IKARIYA, T
    NOYORI, R
    [J]. NATURE, 1994, 368 (6468) : 231 - 233
  • [32] Homogeneous catalysis in supercritical fluids: Hydrogenation of supercritical carbon dioxide to formic acid, alkyl formates, and formamides
    Jessop, PG
    Hsiao, Y
    Ikariya, T
    Noyori, R
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (02) : 344 - 355
  • [33] Jutand A, 1998, EUR J ORG CHEM, V1998, P1811
  • [34] A one-pot procedure for the regiocontrolled synthesis of allyltriazoles via the Pd-Cu bimetallic catalyzed three-component coupling reaction of nonactivated terminal alkynes, allyl carbonate, and trimethylsilyl azide
    Kamijo, S
    Jin, T
    Huo, ZB
    Yamamoto, Y
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (07) : 2386 - 2393
  • [35] Alkyl carbonates:: Efficient three component coupling of aliphatic alcohols, CO2, and alkyl halides in the presence of Cs2CO3
    Kim, SI
    Chu, FX
    Dueno, EE
    Jung, KW
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (13) : 4578 - 4579
  • [36] Synthesis of dimethyl carbonate from carbon dioxide catalyzed by titanium alkoxides with polyether-type ligands
    Kohno, Kazufumi
    Chol, Jun-Chul
    Ohshima, Yoshihiro
    Yasuda, Hiroyuki
    Sakakura, Toshiyasu
    [J]. CHEMSUSCHEM, 2008, 1 (03) : 186 - 188
  • [37] Efficient homogeneous catalysis in the reduction of CO2 to CO
    Laitar, DS
    Müller, P
    Sadighi, JP
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (49) : 17196 - 17197
  • [38] Synthesis of diphenyl carbonate from phenol and carbon dioxide in carbon tetrachloride with zinc halides as catalyst
    Li, Zhenhuan
    Qin, Zhangfeng
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 264 (1-2) : 255 - 259
  • [39] Selective N,N-dibenzylation of primary aliphatic amines with dibenzyl carbonate in the presence of phosphonium salts
    Loris, A
    Perosa, A
    Selva, M
    Tundo, P
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (11) : 3953 - 3956
  • [40] REACTION OF OXIMES WITH DIMETHYL CARBONATE - A NEW ENTRY TO 3-METHYL-4,5-DISUBSTITUTED-4-OXAZOLIN-2-ONES
    MARQUES, CA
    SELVA, M
    TUNDO, P
    MONTANARI, F
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (21) : 5765 - 5770
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