Synthesis and characterization of a new conducting polymer composite

被引:18
作者
Abdi, Mahnaz M. [1 ]
Mahmud, H. N. M. Ekramul [2 ]
Kassim, Anuar [1 ]
Yunus, Wan Mahmood Mat [3 ]
Talib, Zainal Abidin [3 ]
Haron, Mohd Jelas [1 ]
机构
[1] Univ Putra Malaysia, Fac Sci, Dept Chem, Serdang 43400, Selangor, Malaysia
[2] Univ Teknol MARA UiTM, Fac Chem Engn, Shah Alam 40450, Selangor, Malaysia
[3] Univ Putra Malaysia, Fac Sci, Dept Phys, Serdang 43400, Selangor, Malaysia
关键词
POLYPYRROLE; CHITOSAN; DYNAMICS; BEHAVIOR; SPECTRA;
D O I
10.1134/S1560090410110059
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Organic conductive composite films have been synthesized by electropolymerization of pyrrole in the presence of chitosan and p-toluene sulfonic acid sodium salt. The obtained conductive polymer composite films have been characterized by Fourier Transform Infrared spectroscopy, dynamic mechanical analysis, scanning electron microscopy, X-ray diffraction and conductivity measurements. The prepared polymer composite films had the amorphous structure and exhibited the enhanced conductivity and mechanical properties due to the presence of chitosan in the composite films.
引用
收藏
页码:662 / 669
页数:8
相关论文
共 29 条
[21]   Study of polaron and bipolaron states in polypyrrole by in situ Raman spectroelectrochemistry [J].
Santos, M. J. L. ;
Brolo, A. G. ;
Girotto, E. M. .
ELECTROCHIMICA ACTA, 2007, 52 (20) :6141-6145
[22]   A novel bio-inorganic bone implant containing deglued bone, chitosan and gelatin [J].
Saraswathy, G ;
Pal, S ;
Rose, C ;
Sastry, TP .
BULLETIN OF MATERIALS SCIENCE, 2001, 24 (04) :415-420
[23]   PHYSICAL-PROPERTIES OF POLYPYRROLE FILMS CONTAINING SULFONATED METALLOPHTHALOCYANINE ANIONS [J].
SAUNDERS, BR ;
MURRAY, KS ;
FLEMING, RJ .
SYNTHETIC METALS, 1992, 47 (02) :167-178
[24]   LATTICE-DYNAMICS AND VIBRATIONAL-SPECTRA OF PRISTINE AND DOPED POLYPYRROLE - EFFECTIVE CONJUGATION COORDINATE [J].
TIAN, B ;
ZERBI, G .
JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (06) :3892-3898
[25]   MORPHOLOGY OF CONDUCTING ORGANIC POLYMERS - POLYTHIOPHENE AND POLY(3-METHYL THIOPHENE) [J].
TOURILLON, G ;
GARNIER, F .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1984, 22 (01) :33-39
[26]   Morphology and thermostability of polypyrrole prepared from SDBS aqueous solution [J].
Xing, Shuangxi ;
Zhao, Guoku .
POLYMER BULLETIN, 2006, 57 (06) :933-943
[27]   Studies on lithium acetate doped chitosan conducting polymer system [J].
Yahya, MZA ;
Arof, AK .
EUROPEAN POLYMER JOURNAL, 2002, 38 (06) :1191-1197
[28]   Synthesis of novel sunflower-like silica/polypyrrole nanocomposites via self-assembly polymerization [J].
Yang, XM ;
Dai, TY ;
Lu, Y .
POLYMER, 2006, 47 (01) :441-447
[29]   Hollow nanometer-sized polypyrrole capsules with controllable shell thickness synthesized in the presence of chitosan [J].
Yang, XM ;
Lu, Y .
POLYMER, 2005, 46 (14) :5324-5328