Dirubidium tetrachlorodioxouranium(VI) - Water (1:2)

被引:13
作者
Anson, CE
AlJowder, O
Jayasooriya, UA
Powell, AK
机构
[1] School of Chemical Sciences, University of East Anglia
[2] Chemistry Department, College of Science, University of Bahrain, Isa Town
关键词
D O I
10.1107/S0108270195011723
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, Rb-2[UO2Cl4].2H(2)O, has a [UO2-Cl-4](2-) anion, with close to D-4h (4/mmm) symmetry, a U-O distance of 1.751 (9) Angstrom and U-Cl distances of 2.644 (3) and 2.650 (4) Angstrom. The compound is confirmed to be the dihydrate; the degree of hydration had been controversial.
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页码:279 / 281
页数:3
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