A simple and convenient synthesis of cis/trans-RuH2(Ph2PCH2PPh2)2 and of trans-RuHCl(Ph2PCH2PPh2)2

被引：8

作者：

Hill, GS ^{[1
]}

Holah, DG ^{[1
]}

Hughes, AN ^{[1
]}

Prokopchuk, EM ^{[1
]}

机构：

[1] Lakehead Univ, Dept Chem, Thunder Bay, ON P7B 5E1, Canada

来源：

INORGANICA CHIMICA ACTA | 1998年 / 278卷 / 02期

关键词：

diphosphine complexes; ruthenium complexes; hydride complexes;

D O I：

10.1016/S0020-1693(98)00019-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of a suspension of cis-RuCl2(Ph2PCH2PPh2)(2) in ethanol or 2-propanol with a large excess of KOH leads, in a very clean reaction and in less than 2 min when ethanol is used, to the formation of cis/trans-RuH2(Ph2PCH2PPh2)(2) in yields of up to 90%. Similar treatment of the cis-dichloro complex with a small excess of KOH gives, over a longer period, trans-RuHCl(Ph2PCH2PPh2)(2) in 64% yield and this complex can, in turn, be converted under similar conditions into the cis/trans-dihydride in moderate yields. trans-RuCl2(Ph2PCH2Ph2)(2) is unreactive under these conditions. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：226 / 228

页数：3

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