Catalytic synthesis of thiobutyrolactones via CO insertion into the C-S bond of thietanes in the presence of a heterodinuclear organoplatinum-cobalt complex

被引：28

作者：

Furuya, M ^{[1
]}

Tsutsuminai, S ^{[1
]}

Nagasawa, H ^{[1
]}

Komine, N ^{[1
]}

Hirano, M ^{[1
]}

Komiya, S ^{[1
]}

机构：

[1] Tokyo Univ Agr & Technol, Fac Technol, Dept Appl Chem, Tokyo 1848588, Japan

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 16期

关键词：

D O I：

10.1039/b305799b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heterodinuclear organoplatinum-cobalt complex having a 1,2-bis(diphenylphosphino)ethane ligand (dppe)MePt-Co(CO)(4) catalyzes CO insertion into the C-S bond of thietanes in THF at 100degreesC under 1.0 MPa of CO for 2 h to give gamma-thiobutyrolactone in quantitative yield.

引用

页码：2046 / 2047

页数：2

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