Polystyrene-supported DABCO as a highly efficient and recyclable heterogeneous catalyst for the one-pot synthesis of β-phosphonomalonates

被引：28

作者：

Yu, Ya-Qin ^{[2
]}

Xu, Da-Zhen ^{[1
]}

机构：

[1] Nankai Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Natl Pesticide Engn Res Ctr Tianjin, Tianjin 300071, Peoples R China

[2] Tianjin Normal Univ, Key Lab Water Environm & Resources, Tianjin 300387, Peoples R China

来源：

TETRAHEDRON | 2015年 / 71卷 / 19期

基金：

中国国家自然科学基金;

关键词：

Heterogeneous catalyst; Polystyrene-supported; beta-Phosphonomalonates; Phospha-Michael addition; Recycling; MULTICOMPONENT SYNTHESIS; REUSABLE CATALYST; PHOSPHINE OXIDES; MICHAEL ADDITION; BASE CATALYSTS; INHIBITORS; ALDEHYDES; SOLVENT; ACID; HYDROGENATION;

D O I：

10.1016/j.tet.2015.03.070

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Polystyrene-supported DABCO was employed for the first time as a recyclable heterogeneous basic catalyst for one-pot synthesis of beta-phosphonomalonates via tandem Knoevenagel-phospha-Michael reaction at room temperature. The reaction conditions are mild and the method is operationally simple. The catalyst could be easily separated from the reaction mixture by filtration and recycled six times without activity loss. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：2853 / 2857

页数：5

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