PtM/C catalyst prepared using reverse micelle method for oxygen reduction reaction in PEM fuel cells

被引：104

作者：

Qian, Yangdong ^{[1
,2
]}

Wen, Wen ^{[1
,3
]}

Adcock, Peter A. ^{[1
]}

Jiang, Zheng ^{[2
]}

Hakim, Nazih ^{[1
]}

Saha, Madhu S. ^{[1
]}

Mukerjee, Sanjeev ^{[1
]}

机构：

[1] Northeastern Univ, Dept Chem, Boston, MA 02115 USA

[2] Univ Oxford, Wolfson Catalysis Ctr, Inorgan Chem Lab, Oxford OX1 3QR, England

[3] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2008年 / 112卷 / 04期

关键词：

D O I：

10.1021/jp074929i

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Synthesis of carbo n-supported PtM/C catalysts (M = Co, Cr, or Fe) using a new preparation technique, a reverse micelle method, is reported. The catalysts were characterized by different surface techniques: X-ray diffraction, scanning electron microscope,transmission electron microscope, and energy dispersive X-ray microanalysis. Surface characterization showed that Pt/M nanoparticles on catalysts were synthesized using the reverse micelle method. Pt/M nanoparticles were observed to be uniform spherical objects. The performance of the PtM/C catalysts was tested by the rotating disk electrode technique. A trend of catalytic activity for oxygen reduction reaction (ORR) was obtained: PtCo/C(T, 500) similar to PtCo/C(S) > PtCr/C(S) > PtFe/C(S) similar to Pt/C > PtFe/C(T, 500) similar to PtCr/C(T, 500), showing that PtCo/C-type catalysts had a higher catalytic activity for ORR.

引用

页码：1146 / 1157

页数：12

共 50 条

[21] Development of tellurium-modified carbon catalysts for oxygen reduction reaction in PEM fuel cells [J].

Li, Xuguang ;

Liu, Lingyun ;

Lee, Jong-Won ;

Popov, Branko N. .

JOURNAL OF POWER SOURCES, 2008, 182 (01) :18-23

[22] Electrochemical Behavior of Manganese Oxide Nanoparticles for Oxygen Reduction Reaction Environment in PEM Fuel Cells [J].

Mirshekari, G. R. ;

Shirvanian, A. P. .

POLYMER ELECTROLYTE FUEL CELLS 17 (PEFC 17), 2017, 80 (08) :707-716

[23] A comprehensive review of MXenes as catalyst supports for the oxygen reduction reaction in fuel cells [J].

Ahmad Junaidi, Norhamizah Hazirah ;

Wong, Wai Yin ;

Loh, Kee Shyuan ;

Rahman, Saidur ;

Daud, Wan Ramli Wan .

INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2021, 45 (11) :15760-15782

[24] Oxygen reduction on a Pt(111) catalyst in HT-PEM fuel cells by density functional theory [J].

Sun, Hong ;

Li, Jie ;

Almheiri, Saif ;

Xiao, Jianyu .

AIP ADVANCES, 2017, 7 (08)

[25] Non-precious metal oxygen reduction catalyst for PEM fuel cells based on nitroaniline precursor [J].

Wood, Thomas E. ;

Tan, Zhongshu ;

Schmoeckel, Alison K. ;

O'Neill, David ;

Atanasoski, Radoslav .

JOURNAL OF POWER SOURCES, 2008, 178 (02) :510-516

[26] Electrocatalysts for PEM fuel cell oxygen reduction reaction: Challenges and perspectives [J].

Zhang, Jiujun .

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 239

[27] Lattice Boltzmann simulation of oxygen diffusion and electrochemical reaction inside catalyst layer of PEM fuel cells [J].

Deng, Hao ;

Hou, Yuze ;

Chen, Wenmiao ;

Pan, Fengwen ;

Jiao, Kui .

INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2019, 143

[28] Preparation of PtAg/C catalysts for the oxygen reduction in PEM fuel cells: comparison of ultrasonical and mechanical methods as the catalyst ink dispersion technique [J].

Aras, Nida ;

Guldur, Cigdem ;

Gunes, Silver .

ARABIAN JOURNAL FOR SCIENCE AND ENGINEERING, 2023, 48 (12) :15895-15902

[29] Preparation of PtAg/C catalysts for the oxygen reduction in PEM fuel cells: comparison of ultrasonical and mechanical methods as the catalyst ink dispersion technique [J].

Nida Aras ;

Çiğdem Güldür ;

Silver Güneş .

Arabian Journal for Science and Engineering, 2023, 48 :15895-15902

[30] PtOX/C based catalysts with high metal loading for oxygen reduction in PEM fuel cells [J].

Reetz, MT ;

Schulenburg, H ;

Weidenthaler, C ;

Spliethoff, B ;

Dreier, A ;

Bongard, H ;

Lopez, M .

NANOFAIR 2003: NEW IDEAS FOR INDUSTRY, 2003, 1803 :243-246

← 1 2 3 4 5 →