Optimizing the distribution and proportion of various active sites for better NH3-SCR property over Cu/SSZ-13

The Cu/SSZ-13 catalyst with Si/Al ratio of 10 and Cu/Al ratio in the range of 0.005 to 0.5 was synthesized by ion exchange method. The effect of Cu/Al ratio on the performance, selectivity, and active center of the catalyst SCR was studied. The samples with too low Cu/Al ratio have low catalytic activity in the entire temperature range due to the small number of active sites. The samples with too high Cu/Al ratio have good performance in the low temperature range due to the large number of active sites. However, a large amount of copper that has not undergone ion exchange will generate CuO, which greatly enhances the oxidation of NH3 at high temperatures, which in turn leads to a decrease in catalytic performance at high temperatures. XRD and BET experiments show that all catalyst samples have good CHA crystal structure and microporous structure, and the pore size is mostly about 2 nm. In situ DRIFTS analysis shows that when the Cu/Al ratio is low, the proportion of Z(2)Cu in the active sites is higher, and the stability of the catalyst is enhanced. When the copper-aluminum ratio is high, the proportion of ZCuOH increases, and the low-temperature activity of the catalyst is higher.