Vapor-liquid equilibrium and volumetric measurements for binary mixtures of 1,4-dioxane with isomeric chlorobutanes

被引：17
|
作者：
Reyes, A [1 ]
Haro, M [1 ]
Gascón, I [1 ]
Artigas, H [1 ]
Lafuente, C [1 ]
机构：
[1] Univ Zaragoza, Fac Ciencias, Dept Quim Organ Quim Fis, E-50009 Zaragoza, Spain
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2003年 / 48卷 / 04期
关键词：
D O I：
10.1021/je020185k
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Volumetric and isobaric vapor-liquid equilibrium measurements are reported for 1,4-dioxane + 1-chlorobutane, + 2-chlorobutane, + 2-methyl-1-chloropropane, and + 2-chloro-2-methylpropane. From density measurements, excess volumes have been calculated and correlated with a Redlich-Kister equation. The VLE data are thermodynamically consistent and were well correlated with Margules, Van Laar, Wilson, NRTL, and UNIQUAC equations. The VLE results have been compared to the predictions by the UNIFAC and ASOG methods.
引用
收藏
页码：887 / 891
页数：5
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