Synthesis and Tuning Optical Nonlinear Properties of Molecular Crystals of Benzothiadiazole

被引：52

作者：

Chen, Songhua ^{[1
,2
]}

Li, Yongjun ^{[1
]}

Yang, Wenlong ^{[1
,2
]}

Chen, Nan ^{[1
,2
]}

Liu, Huibiao ^{[1
]}

Li, Yuliang ^{[1
]}

机构：

[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2010年 / 114卷 / 35期

关键词：

ABSORPTION CROSS-SECTIONS; CONJUGATED POLYMERS; ORGANIC MATERIALS; TERMINAL ALKYNES; DERIVATIVES; DESIGN; DONOR; 2,1,3-BENZOTHIADIAZOLES; FLUOROPHORES; CHROMOPHORES;

D O I：

10.1021/jp103159b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We described the synthesis and characterization of four kinds of donor-acceptor systems of benzothiadiazole derivatives (BTDs). The crystal packing styles of BTDs can be tuned from the centrosymmetric triclinic crystal system to the noncentrosymmetric orthorhombic system. The nonlinear absorption and nonlinear refraction of BTDs were studied by using the Z-scan technique at 532 nm at 4 ns pulse. The results indicated that all of them exhibit third-order nonlinear optical properties including nonlinear absorption and refractive effects.

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收藏

页码：15109 / 15115

页数：7

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