Guest-to-Host Transmission of Structural Changes for Stimuli-Responsive Adsorption Property

被引：318
|
作者：
Yanai, Nobuhiro [1 ]
Uemura, Takashi [1 ]
Inoue, Masafumi [1 ]
Matsuda, Ryotaro [2 ,3 ]
Fukushima, Tomohiro [1 ]
Tsujimoto, Masahiko [3 ]
Isoda, Seiji [3 ]
Kitagawa, Susumu [1 ,2 ,3 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan
[2] ERATO Kitagawa Integrated Pores Project, Shimogyo Ku, Kyoto 6008815, Japan
[3] Kyoto Univ, Inst Integrated Cell Mat Sci iCeMS, Sakyo Ku, Kyoto 6068501, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 10期
关键词：
POROUS COORDINATION POLYMERS; METAL-ORGANIC FRAMEWORK; MESOPOROUS SILICA; AZOBENZENE; PHOTOISOMERIZATION; CONVERSION; MOLECULES; DESIGN;
D O I：
10.1021/ja2115713
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We show that structural changes of a guest molecule can trigger structural transformations of a crystalline host framework. Azobenzene was introduced into a flexible porous coordination polymer (PCP), and cis/trans isomerizations of the guest azobenzene by light or heat successfully induced structural transformations of the host PCP in a reversible fashion. This guest-to-host structural transmission resulted in drastic changes in the gas adsorption property of the host guest composite, displaying a new strategy for creating stimuli-responsive porous materials.
引用
收藏
页码：4501 / 4504
页数：4
相关论文
共 50 条
  • [1] Host-Guest Stimuli-Responsive Click Chemistry
    Blanco-Gomez, Arturo
    Diaz-Abellas, Mauro
    Montes de Oca, Ivan
    Peinador, Carlos
    Pazos, Elena
    Garcia, Marcos D.
    CHEMISTRY-A EUROPEAN JOURNAL, 2024, 30 (33)
  • [2] Stimuli-responsive polymeric materials functioning via host–guest interactions
    Yoshinori Takashima
    Akira Harada
    Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2017, 88 : 85 - 104
  • [3] A Stimuli-Responsive Nanopore Based on a Photoresponsive Host-Guest System
    Yi-Lun Ying
    Junji Zhang
    Fu-Na Meng
    Chan Cao
    Xuyang Yao
    Itamar Willner
    He Tian
    Yi-Tao Long
    Scientific Reports, 3
  • [4] A Stimuli-Responsive Nanopore Based on a Photoresponsive Host-Guest System
    Ying, Yi-Lun
    Zhang, Junji
    Meng, Fu-Na
    Cao, Chan
    Yao, Xuyang
    Willner, Itamar
    Tian, He
    Long, Yi-Tao
    SCIENTIFIC REPORTS, 2013, 3
  • [5] Control of light transmission in polymer gels by stimuli-responsive guest microparticles
    Suzuki, A
    Sanda, K
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1999, 38 (9A): : 5204 - 5211
  • [6] Advanced stimuli-responsive host-guest biomaterials for treating bacterial infections
    You, Yuhao
    Sun, Hui
    Cheng, Ziying
    Xu, Xinyuan
    Li, Jianshu
    POLYMER, 2024, 307
  • [7] Dual Stimuli-Responsive, Rechargeable Micropumps via "Host-Guest" Interactions
    Patra, Debabrata
    Zhang, Hua
    Sengupta, Samudra
    Sen, Ayusman
    ACS NANO, 2013, 7 (09) : 7674 - 7679
  • [8] Stimuli-responsive polymeric materials functioning via host-guest interactions
    Takashima, Yoshinori
    Harada, Akira
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2017, 88 (3-4) : 85 - 104
  • [9] Stimuli-responsive structural changes in metal-organic frameworks
    Liu, Zhanning
    Zhang, Lu
    Sun, Daofeng
    CHEMICAL COMMUNICATIONS, 2020, 56 (66) : 9416 - 9432
  • [10] Stimuli-Responsive Host-Guest Systems Based on the Recognition of Cryptands by Organic Guests
    Zhang, Mingming
    Yan, Xuzhou
    Huang, Feihe
    Niu, Zhenbin
    Gibson, Harry W.
    ACCOUNTS OF CHEMICAL RESEARCH, 2014, 47 (07) : 1995 - 2005
12345