Electrophoretic deposition of CoFe2O4 films from aqueous suspensions

被引:6
作者
Jian, Gang [1 ]
Zhao, Jun [1 ]
Zhou, Dongxiang [1 ]
Fu, Qiuyun [1 ]
机构
[1] Huazhong Univ Sci & Technol, Dept Elect Sci & Technol, Wuhan 430074, Hubei, Peoples R China
基金
中国国家自然科学基金;
关键词
Suspensions; Electrophoretic deposition; CoFe2O4; Preferential orientations; THIN-FILMS; MAGNETIC-PROPERTIES; FOILS;
D O I
10.1016/j.ceramint.2012.01.014
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
CoFe2O4 nano-particles with average size of similar to 40 nm were synthesized via the chemical coprecipitation method. PAMA-NH4 was used as dispersant to improve the stability of aqueous suspensions. Zeta potential and sediment volumes were tested to study the effects of pH and dispersant amounts on the stability of suspensions. The most stable suspension was obtained when using 0.6 wt.% PAMA-NH4 as dispersant at pH = 10. Conductivity results showed that thoroughly dispersed suspensions were formed after being ultrasonic agitated for 30 min. CoFe2O4 films on Al2O3/Pt substrates fabricated via EPD sintered at 1250 degrees C exhibited preferentially oriented structure. The XRD analyses showed (2 2 0) and (5 1 1) were the preferential orientations. Anisotropy was also observed in magnetic hysteresis loops. Stronger ferromagnetic effect was observed in the in-plane orientation, with saturation magnetization of similar to 290 emu/cm(3). (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:3707 / 3711
页数:5
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