Synthesis of Cu2ZnSnS4 thin film from mixed solution of Cu2SnS3 nanoparticles and Zn ions

被引：0

作者：

Tong, Zheng-fu ^{[1
]}

Yang, Jia ^{[1
]}

Yan, Chang ^{[2
]}

Hao, Meng-meng ^{[1
]}

Liu, Fang-yang ^{[1
,2
]}

Jiang, Liang-xing ^{[1
]}

Lai, Yan-qing ^{[1
]}

Li, Jie ^{[1
]}

Liu, Ye-xiang ^{[1
]}

机构：

[1] Cent S Univ, Sch Met & Environm, Changsha 410083, Hunan, Peoples R China

[2] Univ New South Wales, Sch Photovolta & Renewable Energy Engn, Australian Ctr Adv Photovolta, Sydney, NSW 2052, Australia

来源：

TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA | 2016年 / 26卷 / 08期

基金：

中国国家自然科学基金;

关键词：

Cu2ZnSnS4 thin film; Cu2SnS3; nanoparticle; Zn ion; electrocatalytic; dye-sensitized solar cells; SENSITIZED SOLAR-CELLS; COUNTER ELECTRODE; SULFURIZATION; FABRICATION; PRECURSORS; ABSORBER; GROWTH; SNS2;

D O I：

10.1016/S1003-6326(16)64282-6

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

The Cu2ZnSnS4 thin film was prepared by a facile solution method without vacuum environment and toxic substance. The formation mechanism of the film was studied by transmission electron microscopy (TEM), X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and Raman scattering measurements. Through cyclic voltammetry and photo-electricity tests, the electrocatalytic activity of the prepared film as the counter electrode of dye-sensitized solar cell was also studied. The results show that the mixed precursor solution mainly consists of Cu2SnS3 nanoparticles and Zn ions. After 550 degrees C annealing process on the precursor film prepared from the mixed solution, Cu2ZnSnS4 thin film is obtained. Besides, it is found that the prepared Cu2ZnSnS4 thin film has the electrocatalytic activity toward the redox reaction of I-3(-)/I- and the dye-sensitized solar cell with the prepared Cu2ZnSnS4 thin film as the counter electrode achieves the efficiency of 1.09%.

引用

页码：2102 / 2108

页数：7

共 34 条

[1] A High Efficiency Electrodeposited Cu2ZnSnS4 Solar Cell [J].

Ahmed, Shafaat ;

Reuter, Kathleen B. ;

Gunawan, Oki ;

Guo, Lian ;

Romankiw, Lubomyr T. ;

Deligianni, Hariklia .

ADVANCED ENERGY MATERIALS, 2012, 2 (02) :253-259

[2] One-step diffusion membrane assisted CBD synthesis and characterization of Cu2SnS3 thin films [J].

Becerra, R. A. ;

Correa, J. M. ;

Suarez, H. ;

Gordillo, G. .

21ST LATIN AMERICAN SYMPOSIUM ON SOLID STATE PHYSICS (SLAFES XXI), 2014, 480

[3] Aqueous dye-sensitized solar cells [J].

Bella, Federico ;

Gerbaldi, Claudio ;

Barolo, Claudia ;

Graetzel, Michael .

CHEMICAL SOCIETY REVIEWS, 2015, 44 (11) :3431-3473

[4] Structural and optical properties of Cu2SnS3 sprayed thin films [J].

Bouaziz, M. ;

Amlouk, M. ;

Belgacem, S. .

THIN SOLID FILMS, 2009, 517 (07) :2527-2530

[5] Fabrication of Cu2ZnSnS4 films by sulfurization of Cu/ZnSn/Cu precursor layers in sulfur atmosphere for solar cells [J].

Chalapathy, R. B. V. ;

Jung, Gwang Sun ;

Ahn, Byung Tae .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2011, 95 (12) :3216-3221

[6]

Chen Ai-lian, 2014, Chinese Journal of Nonferrous Metals, V24, P981

[7] A study of ternary Cu2SnS3 and Cu3SnS4 thin films prepared by sulfurizing stacked metal precursors [J].

Fernandes, P. A. ;

Salome, P. M. P. ;

da Cunha, A. F. .

JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2010, 43 (21)

[8] In-depth resolved Raman scattering analysis for the identification of secondary phases: Characterization of Cu2ZnSnS4 layers for solar cell applications [J].

Fontane, X. ;

Calvo-Barrio, L. ;

Izquierdo-Roca, V. ;

Saucedo, E. ;

Perez-Rodriguez, A. ;

Morante, J. R. ;

Berg, D. M. ;

Dale, P. J. ;

Siebentritt, S. .

APPLIED PHYSICS LETTERS, 2011, 98 (18)

[9] Fabrication of 7.2% Efficient CZTSSe Solar Cells Using CZTS Nanocrystals [J].

Guo, Qijie ;

Ford, Grayson M. ;

Yang, Wei-Chang ;

Walker, Bryce C. ;

Stach, Eric A. ;

Hillhouse, Hugh W. ;

Agrawal, Rakesh .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (49) :17384-17386

[10] Crystallization behaviour of co-sputtered Cu2ZnSnS4 precursor prepared by sequential sulfurization processes [J].

Han, Junhee ;

Shin, Seung Wook ;

Gang, Myeong Gil ;

Kim, Jin Hyeok ;

Lee, Jeong Yong .

NANOTECHNOLOGY, 2013, 24 (09)

← 1 2 3 4 →