A comparative study on different functionalized mesoporous silica nanomagnetic sorbents for efficient extraction of parabens

被引:10
作者
Mehdinia, Ali [1 ]
Bahrami, Mahnaz [2 ]
Mozaffari, Shahla [2 ]
机构
[1] Iranian Natl Inst Oceanog & Atmospher Sci, Dept Marine Sci, Tehran, Iran
[2] Payam Noor Univ, Dept Chem, Tehran, Iran
基金
美国国家科学基金会;
关键词
Functionalized nanomagnetic sorbents; Solid-phase extraction; Nanocamposite; Parabens; Cosmetic products; SOLID-PHASE EXTRACTION; MAGNETIC-MATERIALS; NANOPARTICLES; GRAPHENE; WATER; OXIDE; MICROEXTRACTION; FABRICATION;
D O I
10.1007/s13738-015-0626-8
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Different silica-based magnetic sorbents including mesoporous silica-Fe3O4 nanocomposite (Fe3O4@MCM-41), amino-functionalized mesoporous silica-Fe3O4 nanocomposite (Fe3O4@MCM-41-NH2) and graphene oxide/amino-functionalized mesoporous silica-Fe3O4 nanocomposite (Fe3O4@MCM-41-NH2-GO) were synthesized and their extraction efficiencies were compared in solid-phase extraction procedure of important parabens prior to gas chromatography-flame ionization detection. The sorbents extraction efficiencies followed the order of Fe3O4@MCM-41-NH2 > Fe3O4@MCM-41-NH2-GO > Fe3O4@MCM-41. Parameters affecting SPE procedure including amount of sorbent, eluting solvent type, adsorption and desorption times, and ionic strength were studied and optimized. The method's performance was studied in terms of accuracy, linearity, precision and limits of detection. Detection limits of the method were < 0.9 A mu g L-1 and linearity was in the range of 10-1000 A mu g L-1. Finally, the applicability of the proposed method was demonstrated for extraction of selected parabens in some cosmetic products. Good quantitative recoveries for spiked samples (85-107 %) and satisfactory precision (RSD a parts per thousand currency sign 5.6 %) were also obtained.
引用
收藏
页码:1543 / 1552
页数:10
相关论文
共 50 条
[31]   Comparative Study of Solid-Phase Extraction of Dissolved Organic Matter from Oilfield-Produced Brine by Different Sorbents [J].
Yang, Keli ;
Zhang, Yaoling ;
Dong, Yaping ;
Nie, Zhen ;
Li, Wu .
ENVIRONMENTAL ENGINEERING SCIENCE, 2017, 34 (09) :675-686
[32]   One-step separation of the recombinant protein by using the amine-functionalized magnetic mesoporous silica nanoparticles; an efficient and facile approach [J].
Tavakoli, Zahra ;
Rasekh, Behnam ;
Yazdian, Fatemeh ;
Maghsoudi, Amir ;
Soleimani, Mehdi ;
Mohammadnejad, Javad .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2019, 135 :600-608
[33]   Determination of personal care products in water using UHPLC-MS after solid phase extraction with mesoporous silica-based MCM-41 functionalized with cyanopropyl groups [J].
Kharbouche, Leila ;
Gil Garcia, Maria Dolores ;
Lozano, Ana ;
Hamaizi, Hadj ;
Martinez Galera, Maria .
JOURNAL OF SEPARATION SCIENCE, 2020, 43 (11) :2142-2153
[34]   Cubic Mesoporous Silica Material as a Highly Efficient Solid Phase Extraction Sorbent for Bisphenol A, Tert-Nonylphenol from Water [J].
Jin, Zhongxiu ;
Xu, Yuanyuan ;
Lin, Shilei ;
Sheng, Jie .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2016, 16 (06) :5833-5838
[35]   An infrared study of adsorbed metal ions on modified silica: Comparative chelation between mercury, cadmium, and lead divalent ions to silica functionalized with ortho- and para-aminothiophenoles [J].
Hamid, Amer A. G. Al Abdel ;
Kanan, Sofian .
VIBRATIONAL SPECTROSCOPY, 2011, 57 (02) :254-260
[36]   Effective Use of Mesoporous Silica Filler: Comparative Study on Thermal Stability and Transparency of Silicone Rubbers Loaded with Various Kinds of Silica Particles [J].
Suzuki, Norihiro ;
Kamachi, Yuichiro ;
Takai, Kimiko ;
Kiba, Shosuke ;
Sakka, Yoshio ;
Miyamoto, Nobuyoshi ;
Yamauchi, Yusuke .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, 2014 (17) :2773-2778
[37]   pH-Responsive sulphonated mesoporous silica: a comparative drug release study [J].
Ayad, Mohamad M. ;
Salahuddin, Nehal A. ;
Torad, Nagy L. ;
Abu El-Nasr, Ahmed .
RSC ADVANCES, 2016, 6 (63) :57929-57940
[38]   Mannose-Functionalized Mesoporous Silica Nanoparticles for Efficient Two-Photon Photodynamic Therapy of Solid Tumors [J].
Gary-Bobo, Magali ;
Mir, Youssef ;
Rouxel, Cedric ;
Brevet, David ;
Basile, Ilaria ;
Maynadier, Marie ;
Vaillant, Ophelie ;
Mongin, Olivier ;
Blanchard-Desce, Mireille ;
Morere, Alain ;
Garcia, Marcel ;
Durand, Jean-Olivier ;
Raehm, Laurence .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (48) :11425-11429
[39]   Amino Acid-functionalized hollow mesoporous silica nanospheres as efficient biocompatible drug carriers for anticancer applications [J].
Ezzati, Nasim ;
Mahjoub, Ali Reza ;
Shahrnoy, Abdolghafar Abolhosseini ;
Syrgiannis, Zois .
INTERNATIONAL JOURNAL OF PHARMACEUTICS, 2019, 572
[40]   Comparative study of different sorbents for clean-up for pyrethroid analysis in cocoa powder by GC-ECD: A preliminary study [J].
Yusiasih, R. ;
Endah, E. S. ;
Ariyani, M. ;
Koesmawati, T. A. ;
Pitoi, M. M. .
PROCEEDING OF THE 4TH INTERNATIONAL SYMPOSIUM ON GREEN TECHNOLOGY FOR VALUE CHAINS 2019, 2020, 483