Particle size studies to reveal crystallization mechanisms of the metal organic framework HKUST-1 during sonochemical synthesis

被引：51
作者：
Armstrong, Mitchell R. [1 ]
Senthilnathan, Sethuraman [1 ]
Balzer, Christopher J. [1 ]
Shan, Bohan [1 ]
Chen, Liang [2 ]
Mu, Bin [1 ]
机构：
[1] Arizona State Univ, Sch Engn Mat Transport & Energy, 501 East Tyler Mall, Tempe, AZ 85281 USA
[2] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China
来源：
ULTRASONICS SONOCHEMISTRY | 2017年 / 34卷
关键词：
Sonochemistry; Ultrasound-assisted synthesis; Metal organic frameworks; CuBTC or HKUST-1; Crystallization; Particle size distribution; INTERPARTICLE COLLISIONS DRIVEN; SEPARATION; CRYSTALS; ZIF-8;
D O I：
10.1016/j.ultsonch.2016.06.011
中图分类号：
O42 [声学];
学科分类号：
070206 ; 082403 ;
摘要：
Systematic studies of key operating parameters for the sonochemical synthesis of the metal organic framework (MOF) HKUST-1(also called CuBTC) were performed including reaction time, reactor volume, sonication amplitude, sonication tip size, solvent composition, and reactant concentrations analyzed through SEM particle size analysis. Trends in the particle size and size distributions show reproducible control of average particle sizes between 1 and 4 gm. These results along with complementary studies in sonofragmentation and temperature control were conducted to compare these results to kinetic crystal growth models found in literature to develop a plausible hypothetical mechanism for ultrasound-assisted growth of metal-organic-frameworks composed of a competitive mechanism including constructive solid-on-solid (SOS) crystal growth and a deconstructive sonofragmentation. (C) 2016 Elsevier By. All rights reserved.
引用
收藏
页码：365 / 370
页数：6
相关论文
共 28 条
  • [1] Abrmoff MD., 2004, Image Processing with ImageJ, V11, P36, DOI DOI 10.1201/9781420005615.AX4
  • [2] Applications of Ultrasound to the Synthesis of Nanostructured Materials
    Bang, Jin Ho
    Suslick, Kenneth S.
    [J]. ADVANCED MATERIALS, 2010, 22 (10) : 1039 - 1059
  • [3] Adsorption properties of HKUST-1 toward hydrogen and other small molecules monitored by IR
    Bordiga, S.
    Regli, L.
    Bonino, F.
    Groppo, E.
    Lamberti, C.
    Xiao, B.
    Wheatley, P. S.
    Morris, R. E.
    Zecchina, A.
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (21) : 2676 - 2685
  • [4] INTERPARTICLE COLLISIONS DRIVEN BY ULTRASOUND
    DOKTYCZ, SJ
    SUSLICK, KS
    [J]. SCIENCE, 1990, 247 (4946) : 1067 - 1069
  • [5] HKUST-1 membranes on porous supports using secondary growth
    Guerrero, Victor Varela
    Yoo, Yeonshick
    McCarthy, Michael C.
    Jeong, Hae-Kwon
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (19) : 3938 - 3943
  • [6] EFFECT OF ULTRASONIC VIBRATIONS ON CRYSTALLIZATION PROCESSES
    HEM, SL
    [J]. ULTRASONICS, 1967, 5 (OCT) : 202 - &
  • [7] Separation of Hexane Isomers in a Metal-Organic Framework with Triangular Channels
    Herm, Zoey R.
    Wiers, Brian M.
    Mason, Jarad A.
    van Baten, Jasper M.
    Hudson, Matthew R.
    Zajdel, Pawel
    Brown, Craig M.
    Masciocchi, Norberto
    Krishna, Rajamani
    Long, Jeffrey R.
    [J]. SCIENCE, 2013, 340 (6135) : 960 - 964
  • [8] Simple and Compelling Biomimetic Metal-Organic Framework Catalyst for the Degradation of Nerve Agent Simulants
    Katz, Michael J.
    Mondloch, Joseph E.
    Totten, Ryan K.
    Park, Jin K.
    Nguyen, SonBinh T.
    Farha, Omar K.
    Hupp, Joseph T.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (02) : 497 - 501
  • [9] Facile Syntheses of Metal-organic Framework Cu3(BTC)2(H2O)3 under Ultrasound
    Khan, Nazmul Abedin
    Jhung, Sung Hwa
    [J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2009, 30 (12): : 2921 - 2926
  • [10] Photocatalytic CO2 reduction by a mixed metal (Zr/Ti), mixed ligand metal-organic framework under visible light irradiation
    Lee, Yeob
    Kim, Sangjun
    Kang, Jeung Ku
    Cohen, Seth M.
    [J]. CHEMICAL COMMUNICATIONS, 2015, 51 (26) : 5735 - 5738
123