Effect of steam on coking in the non-catalytic pyrolysis of naphtha components

被引：12

作者：

Lee, JH ^{[1
]}

Kim, KM ^{[1
]}

Kim, SH ^{[1
]}

Lee, CS ^{[1
]}

机构：

[1] Korea Univ, Dept Biol & Chem Engn, Seoul 136701, South Korea

来源：

KOREAN JOURNAL OF CHEMICAL ENGINEERING | 2004年 / 21卷 / 01期

关键词：

coking; reaction equilibrium; naphtha; steam;

D O I：

10.1007/BF02705406

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Coking has presented difficulties in reactions including pyrolysis and steam has been added to reduce coking. In this study, the effect of steam on coking in the pyrolysis of naphtha components was studied thermodynamically and experimentally for non-catalytic tubular reactor systems. The qualitative relations between these two thermodynamic and experimental studies were established. In both studies coking was reduced as the steam ratio increased. However, experimental studies indicated that the reduction was more effective for smaller values of the ratio, leading to an effective ratio of about 0.5, and that weak coking still occurred for the ratio greater than the thermodynamic zero-coke ratio.

引用

页码：252 / 256

页数：5

共 26 条

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