Fabrication and testing of sodium-ion full cell with P2-Na0.67 Ni0.167Co0.167 Mn0.67O2 (Na-NCM) and hard carbon in coin cell and 2 Ah prismatic cell configuration

被引:6
作者
Senthilkumar, M. [1 ]
Satyavani, T. V. S. L. [1 ]
Jagadish, K. [1 ]
Sahoo, P. K. [1 ]
Kumar, A. Srinivas [1 ]
机构
[1] Naval Sci & Technol Lab, Visakhapatnam 530027, Andhra Pradesh, India
关键词
Sodium; Full cell; Prismatic cell; C rates; CATHODE MATERIAL; HIGH-CAPACITY; ELECTROCHEMICAL PROPERTIES; ANODE MATERIALS; HIGH-ENERGY; BATTERIES; P2-TYPE; PERFORMANCE; INSERTION; ELECTRODE;
D O I
10.1016/j.ijhydene.2021.10.220
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Fabrication of sodium-ion full cell (SIFC) with optimized anode and cathode material is in the initial phases. The successful fabrication of full cell is depended on effective improvement in electrode materials and performance of sodium-ion half-cells. Cathode material plays crucial role in the performance of full cell. Sodium-ion full cell was fabricated based P2-type Na0.67Ni0.167Co0.167Mn0.67O2 (Na-NCM) material synthesized by sol-gel process and commercially available hard carbon. The electrochemical properties of NaNCM material and hard carbon were systematically investigated. The hard carbon material achieved a reversible capacity of 210.82 mAh g-1 with initial columbic efficiency of 81.15% in Na/Hard Carbon half-cell. The Na-NCM material exhibits a discharge capacity of 149.27 mAh g-1 at C/20 rate in Na/Na-NCM half cell. The fabricated SIFC in coin cell configuration delivers a specific capacity of 74.6 mAh g-1 at C/20 rate, with 40% of the initial discharge capacity delivered after 100 cycles at C/20 and the columbic efficiency is more than 90%. The coin cell in full cell configuration displays reasonable performance at the rates of C/20 to 3C indicating the capability of high rate performance of anode and cathode materials. The first discharge capacity of fabricated SIFC in prismatic configuration is 2.16Ah. (c) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:1790 / 1803
页数:14
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