The influence of cage size on the reactivity of trimetallic nitride metallofullerenes:: a mono- and bis-methanoadduct of Gd3N@C80 and a monoadduct of Gd3N@C84

被引:39
作者
Chaur, Manuel N. [1 ]
Melin, Frederic [1 ]
Athans, Andreas J. [1 ]
Elliott, Bevan [1 ]
Walker, Kenneth [2 ]
Holloway, Brian C. [2 ]
Echegoyen, Luis [1 ]
机构
[1] Clemson Univ, Dept Chem, Clemson, SC 29634 USA
[2] Luna Innovat Inc, NanoWorks Div, Danville, VA USA
关键词
D O I
10.1039/b804847a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A reactivity study of the higher TNT EMFs of gadolinium is reported here showing that the reactivity substantially decreases when the fullerene cage gets larger.
引用
收藏
页码:2665 / 2667
页数:3
相关论文
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[21]   Isolation and structural characterization of a family of endohedral fullerenes including the large, chiral cage fullerenes Tb3N@C88 and Tb3N@C86 as well as the Ih and D5h isomers of Tb3N@C80 [J].
Zuo, Tianming ;
Beavers, Christine M. ;
Duchamp, James C. ;
Campbell, Anne ;
Dorn, Harry C. ;
Olmstead, Marilyn M. ;
Balch, Alan L. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (07) :2035-2043