The influence of aromatic cations on the geometries of the Bi(III) halide polyhedra. Synthesis and crystal structures of quinolinium, isoquinolinium and 8-hydroxyquinolinium polychlorobismuthate(III) derivatives

被引：38
作者：
Benetollo, F
Bombieri, G
Del Pra, A
Alonzo, G
Bertazzi, N
机构：
[1] Univ Milan, Ist Chim Farmaceut, I-20131 Milan, Italy
[2] CNR, ICTIMA, I-35127 Padua, Italy
[3] Univ Palermo, Dipartimento ITAF, Sez Chim, I-90128 Palermo, Italy
[4] Univ Palermo, Dipartimento Chim Inorgan, I-90128 Palermo, Italy
来源：
INORGANICA CHIMICA ACTA | 2001年 / 319卷 / 1-2期
关键词：
crystal structures; bismuth complexes; halide complexes; quinolinium complexes;
D O I：
10.1016/S0020-1693(01)00436-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The compounds [quinolinium](4)[Bi2Cl10] (1), [isoquinolinium](4)[Bi2Cl10]. 2H(2)O (2) and [8-hydroxyquinolinium](4)[BiCl6]. Cl . 2H(2)O (3) have been obtained by reacting bismuthate oxide and the appropriate base in KCI acid medium. The crystal structures of 1 and 2 consist of quinolinium and isoquinolinium cations, respectively, interacting through hydrogen bonding with [Bi2Cl10](4-) dimers. The different degree of interactions in the two derivatives causes significant differences in the bond distances of the anions. The crystal structure of 3 is made of [BiCl6](3-) and Cl- anions and 8-hydroxyquinolinium cations. Hydrogen bond interactions including the N-bonded and O-bonded H atoms together with an interstitial chlorine atom stabilize the entire crystal structure. (C) 2001 Elsevier Science B.V. All rights reserved.
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页码：49 / 56
页数：8
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