CO-free hydrogen production via dehydrogenation of a Jet A hydrocarbon mixture

被引：28

作者：

Wang, Bo ^{[2
]}

Froment, Gilbert F. ^{[2
]}

Goodman, D. Wayne ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

[2] Texas A&M Univ, Dept Chem Engn, College Stn, TX 77843 USA

来源：

JOURNAL OF CATALYSIS | 2008年 / 253卷 / 02期

关键词：

hydrogen; dehydrogenation; fuel cell; cyclohexane; decalin; Jet A;

D O I：

10.1016/j.jcat.2007.11.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The dehydrogenation of a Jet A hydrocarbon mixture was investigated for the production of hydrogen for fuel cell applications. This process differs from steam/partial oxidation reforming of hydrocarbons in that the hydrogen produced is free of CO, and therefore can be used in low temperature fuel cells without further purification. Because of their relative importance with respect to the spectrum of hydrocarbons in the mixture, cyclohexane and decalin were investigated independently. A hybrid catalyst, Pt/gamma-Al2O3-ZrO2/SO42-, was designed to enhance the hydrogen production yields. (c) 2007 Elsevier Inc. All rights reserved.

引用

页码：239 / 243

页数：5

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