CuCl catalyzed oxidation of aldehydes to carboxylic acids with aqueous tert-butyl hydroperoxide under mild conditions

被引：66

作者：

Mannam, Sreedevi ^{[1
]}

Sekar, G. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India

来源：

TETRAHEDRON LETTERS | 2008年 / 49卷 / 06期

关键词：

copper catalyst; oxidation; aromatic aldehydes; carboxylic acids; selective oxidation;

D O I：

10.1016/j.tetlet.2007.11.198

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxidation of aldehydes to the corresponding carboxylic acids can be performed highly efficiently at room temperature with 70% tertbutyl hydroperoxide (in water) in the presence of a catalytic amount of easily available ligand free CuCl in acetonitrile as solvent under very mild conditions. This oxidation protocol works well for various aldehydes including aliphatic aldehydes and aliphatic dialdehydes. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：1083 / 1086

页数：4

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