Cobalt phthalocyanine as an efficient catalyst for hydrogen evolution reaction

被引：59

作者：

Chen, Lifang ^{[1
]}

Sagar, Rizwan Ur Rehman ^{[1
]}

Chen, Jun ^{[1
]}

Liu, Juan ^{[2
]}

Aslam, Sehrish ^{[3
]}

Nosheen, Farhat ^{[7
]}

Anwar, Tauseef ^{[1
,6
]}

Hussain, Naveed ^{[4
]}

Hou, Xinmei ^{[5
]}

Liang, Tongxiang ^{[1
]}

机构：

[1] Jiangxi Univ Sci & Technol, Coll Rare Earths, 86 Hong Qi Rd, Ganzhou 341000, Peoples R China

[2] Hunan Univ Technol, Sch Packaging & Mat Engn, Zhuzhou 412007, Peoples R China

[3] Harbin Inst Technol, Sch Mat Sci & Engn, Shenzhen Engn Lab Flexible Transparent Conduct Fi, Shenzhen 518055, Peoples R China

[4] Univ Elect Sci & Technol China UESTC, Inst Fundamental & Frontier Sci IFFS, Chengdu, Peoples R China

[5] Univ Sci & Technol Beijing, Collaborat Innovat Ctr Steel Technol, Beijing 100083, Peoples R China

[6] Univ Lahore, Dept Phys, Lahore, Pakistan

[7] Univ Educ, Dept Chem, Div Sci & Technol, Lahore, Pakistan

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2021年 / 46卷 / 37期

基金：

中国国家自然科学基金;

关键词：

Cobalt-phthalocyanine; Graphene oxide; Hydrogen evolution reaction; CARBON NANOTUBES; DOPED GRAPHENE; ELECTROCATALYST; PERFORMANCE; ELECTRODE;

D O I：

10.1016/j.ijhydene.2021.03.075

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrogen production from water splitting is highly desired for the green and clean energy device but remains a great challenge. In this regard, cobalt-phthalocyanine (PyCoPc) and composite of PyCoPc with graphene oxide (GO) were fabricated and used as catalyst for the energy conversion. The as-synthesized PyCoPc/GO exhibits an efficient hydrogen evolution reaction due to the low overpotential-253 mV at a 10 mA cm-2 current density with a Tafel slope-96 mV dec-1 in alkaline media. Our study reveals that the active area of the catalyst was controlled with the help of p p stacking interaction between GO and PyCoPc. Technologically, a highly efficient PyCoPc catalyst was developed for hydrogen evolution reaction. (c) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：19338 / 19346

页数：9

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