Borophene and Boron-Based Nanosheets: Recent Advances in Synthesis Strategies and Applications in the Field of Environment and Energy

被引:61
作者
Chand, Hushan [1 ,2 ]
Kumar, Ashish [1 ,2 ]
Krishnan, Venkata [1 ,2 ]
机构
[1] Indian Inst Technol Mandi, Sch Basic Sci, Mandi 175075, Himachal Prades, India
[2] Indian Inst Technol Mandi, Adv Mat Res Ctr, Mandi 175075, Himachal Prades, India
关键词
borophene; CO; (2) reduction; heterogeneous catalysts; hydrogen storage; supercapacitors; PHONON-MEDIATED SUPERCONDUCTIVITY; PROMISING ANODE MATERIAL; HIGH-RATE CAPABILITY; LI-ION BATTERIES; 2-DIMENSIONAL BORON; HYDROGEN STORAGE; 1ST PRINCIPLES; FEW-LAYER; TRANSPORT-PROPERTIES; CATALYTIC-ACTIVITY;
D O I
10.1002/admi.202100045
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Since the discovery of borophene in 2014, tremendous efforts have been invested in exploring its synthesis methods as well as in exploiting the potential applications. Borophene has been progressively used in the field of chemistry, material science, nanotechnology, and condensed matter physics. This review discusses the physical (thermal, electronic, superconductive, and mechanical) and chemical properties of borophene followed by the advances in the experimental synthesis strategies and finally its applications in the field of environment and energy. Initially, the potential of borophene as a heterogeneous catalyst is discussed in CO2 reduction, N-2 fixation, hydrogen evolution and oxygen evolution reactions followed by its use as a potential material for hydrogen storage, supercapacitors as well as its use as an anode material in batteries. Finally, a detailed summary followed by an outlook on the future potential of borophene as a remarkable material for environment and energy applications is presented.
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页数:31
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共 184 条
[31]  
Feng BJ, 2016, NAT CHEM, V8, P564, DOI [10.1038/nchem.2491, 10.1038/NCHEM.2491]
[32]   THE OXIDATION OF THE BETA-RHOMBOHEDRAL BORON(111) SURFACE [J].
FOO, WC ;
OZCOMERT, JS ;
TRENARY, M .
SURFACE SCIENCE, 1991, 255 (03) :245-258
[33]   Hydrogenated Borophene Shows Catalytic Activity as Solid Acid [J].
Fujino, Asahi ;
Ito, Shin-ichi ;
Goto, Taiga ;
Ishibiki, Ryota ;
Kondo, Junko N. ;
Fujitani, Tadahiro ;
Nakamura, Junji ;
Hosono, Hideo ;
Kondo, Takahiro .
ACS OMEGA, 2019, 4 (09) :14100-14104
[34]   Prediction of phonon-mediated superconductivity in borophene [J].
Gao, Miao ;
Li, Qi-Zhi ;
Yan, Xun-Wang ;
Wang, Jun .
PHYSICAL REVIEW B, 2017, 95 (02)
[35]   What will freestanding borophene nanoribbons look like? An analysis of their possible structures, magnetism and transport properties [J].
Garcia-Fuente, A. ;
Carrete, J. ;
Vega, A. ;
Gallego, L. J. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2017, 19 (02) :1054-1061
[36]   Proposed boron nanotubes [J].
Gindulyte, A ;
Lipscomb, WN ;
Massa, L .
INORGANIC CHEMISTRY, 1998, 37 (25) :6544-6545
[37]   Semiempirical GGA-type density functional constructed with a long-range dispersion correction [J].
Grimme, Stefan .
JOURNAL OF COMPUTATIONAL CHEMISTRY, 2006, 27 (15) :1787-1799
[38]   Simple, Green, and High-Yield Production of Boron-Based Nanostructures with Diverse Morphologies by Dissolution and Recrystallization of Layered Magnesium Diboride Crystals in Water [J].
Gunda, Harini ;
Das, Saroj Kumar ;
Jasuja, Kabeer .
CHEMPHYSCHEM, 2018, 19 (07) :880-891
[39]   Hydrogen storage in Li, Na and Ca decorated and defective borophene: a first principles study [J].
Haldar, Sandip ;
Mukherjee, Sankha ;
Singh, Chandra Veer .
RSC ADVANCES, 2018, 8 (37) :20748-20757
[40]   Orbitally driven giant thermal conductance associated with abnormal strain dependence in hydrogenated graphene-like borophene [J].
He, Jia ;
Li, Dengfeng ;
Ying, Yan ;
Feng, Chunbao ;
He, Junjie ;
Zhong, Chengyong ;
Zhou, Hangbo ;
Zhou, Ping ;
Zhang, Gang .
NPJ COMPUTATIONAL MATERIALS, 2019, 5 (1)