Borophene and Boron-Based Nanosheets: Recent Advances in Synthesis Strategies and Applications in the Field of Environment and Energy

被引:61
作者
Chand, Hushan [1 ,2 ]
Kumar, Ashish [1 ,2 ]
Krishnan, Venkata [1 ,2 ]
机构
[1] Indian Inst Technol Mandi, Sch Basic Sci, Mandi 175075, Himachal Prades, India
[2] Indian Inst Technol Mandi, Adv Mat Res Ctr, Mandi 175075, Himachal Prades, India
关键词
borophene; CO; (2) reduction; heterogeneous catalysts; hydrogen storage; supercapacitors; PHONON-MEDIATED SUPERCONDUCTIVITY; PROMISING ANODE MATERIAL; HIGH-RATE CAPABILITY; LI-ION BATTERIES; 2-DIMENSIONAL BORON; HYDROGEN STORAGE; 1ST PRINCIPLES; FEW-LAYER; TRANSPORT-PROPERTIES; CATALYTIC-ACTIVITY;
D O I
10.1002/admi.202100045
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Since the discovery of borophene in 2014, tremendous efforts have been invested in exploring its synthesis methods as well as in exploiting the potential applications. Borophene has been progressively used in the field of chemistry, material science, nanotechnology, and condensed matter physics. This review discusses the physical (thermal, electronic, superconductive, and mechanical) and chemical properties of borophene followed by the advances in the experimental synthesis strategies and finally its applications in the field of environment and energy. Initially, the potential of borophene as a heterogeneous catalyst is discussed in CO2 reduction, N-2 fixation, hydrogen evolution and oxygen evolution reactions followed by its use as a potential material for hydrogen storage, supercapacitors as well as its use as an anode material in batteries. Finally, a detailed summary followed by an outlook on the future potential of borophene as a remarkable material for environment and energy applications is presented.
引用
收藏
页数:31
相关论文
共 184 条
[1]   First-Principles Investigation of Borophene as a Monolayer Transparent Conductor [J].
Adamska, Lyudmyla ;
Sadasiyam, Sridhar ;
Foley, Jonathan J. ;
Darancet, Pierre ;
Sharifzadeh, Sahar .
JOURNAL OF PHYSICAL CHEMISTRY C, 2018, 122 (07) :4037-4045
[2]   Boron: Elementary Challenge for Experimenters and Theoreticians [J].
Albert, Barbara ;
Hillebrecht, Harald .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (46) :8640-8668
[3]   High-capacity hydrogen storage by metallized graphene [J].
Ataca, C. ;
Akturk, E. ;
Ciraci, S. ;
Ustunel, H. .
APPLIED PHYSICS LETTERS, 2008, 93 (04)
[4]   A brief review on synthesis, properties and lithium-ion battery applications of borophene [J].
Ayodhya, Dasari ;
Veerabhadram, Guttena .
FLATCHEM, 2020, 19
[5]  
Bando Y., 2014, SMALL, V10, P177
[6]   Nitrogen-decorated borophene: An empowering contestant for hydrogen storage [J].
Baraiya, Bhumi A. ;
Som, Narayan N. ;
Mankad, Venu ;
Wu, Guangfen ;
Wang, Jinlan ;
Jha, Prafulla K. .
APPLIED SURFACE SCIENCE, 2020, 527
[7]   Highly Conductive Boron Nanotubes: Transport Properties, Work Functions, and Structural Stabilities [J].
Bezugly, Viktor ;
Kunstmann, Jens ;
Grundkoetter-Stock, Bernhard ;
Frauenheim, Thomas ;
Niehaus, Thomas ;
Cuniberti, Gianaurelio .
ACS NANO, 2011, 5 (06) :4997-5005
[8]   Hydrogen production from natural gas, sequestration of recovered CO2 in depleted gas wells and enhanced natural gas recovery [J].
Blok, K ;
Williams, RH ;
Katofsky, RE ;
Hendriks, CA .
ENERGY, 1997, 22 (2-3) :161-168
[9]   Systematic ab initio investigation of bare boron clusters: Determination of the geometry and electronic structures of B-n (n=2-14) [J].
Boustani, I .
PHYSICAL REVIEW B, 1997, 55 (24) :16426-16438
[10]   New boron based nanostructured materials [J].
Boustani, I ;
Quandt, A ;
Hernández, E ;
Rubio, A .
JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (06) :3176-3185