Recent Advance in Transition-Metal-Catalyzed Silylation of C-H Bonds

被引：19

作者：

Huang, Hongtai ^{[1
]}

Li, Tao ^{[1
]}

Wang, Jiazhuang ^{[1
]}

Qin, Guiping ^{[1
]}

Xiao, Tiebo ^{[1
]}

机构：

[1] Kunming Univ Sci & Technol, Fac Sci, Kunming 650500, Yunnan, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 39卷 / 06期

基金：

中国国家自然科学基金;

关键词：

C-H functionalization; transition-metal catalysis; silylation; organosilanes; INTRAMOLECULAR SILYLATION; DEHYDROGENATIVE CYCLIZATION; C(SP(3))-H SILYLATION; SILICON; EFFICIENT; TRACELESS; COMPLEX; ARENES;

D O I：

10.6023/cjoc201903078

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Organosilicon compounds play an important role in pharmaceutical chemistry, material science and organic synthesis. Transition-metal-catalyzed direct silylation of C-H bond, as one of the most concise and efficient methods for the synthesis of organosilanes, has developed rapidly in recent years. In this paper, the recent advance in transition-metal-catalyzed silylation of C-H bonds since 2015 is mainly reviewed.

引用

页码：1511 / 1521

页数：11

共 73 条

[1] Bright blue luminescent pyrenyl-containing organosilicon compounds with contrasting charge transport functionality -: SiPh2(p-C6H4-pyrenyl)(p-C6H4-N-benzimidazolyl) and SiPh2(p-C6H4-pyrenyl)[p-C6H4-NPh(1-naph)]
Bai, Dongren
Han, Shijin
Lu, Zheng-Hong
Wang, Suning
[J]. CANADIAN JOURNAL OF CHEMISTRY, 2008, 86 (03) : 230 - 237
[2] Polymeric and ceramic silicon-based coatings - a review
Barroso, Gilvan
Li, Quan
Bordia, Rajendra K.
Motz, Guenter
[J]. JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (05) : 1936 - 1963
[3] Regio- and Stereoselective Dehydrogenative Silylation and Hydrosilylation of Vinylarenes Catalyzed by Ruthenium Alkylidenes
Bokka, Apparao
Jeon, Junha
[J]. ORGANIC LETTERS, 2016, 18 (20) : 5324 - 5327
[4] Traceless Silylation of β-C(sp3)-H Bonds of Alcohols via Perfluorinated Acetals
Bunescu, Ala
Butcher, Trevor W.
Hartwig, John F.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (04) : 1502 - 1507
[5] Catalytic Silylation of Unactivated C-H Bonds
Cheng, Chen
Hartwig, John F.
[J]. CHEMICAL REVIEWS, 2015, 115 (17) : 8946 - 8975
[6] Ru-catalysed C-H silylation of unprotected gramines, tryptamines and their congeners
Devaraj, K.
Sollert, C.
Juds, C.
Gates, P. J.
Pilarski, L. T.
[J]. CHEMICAL COMMUNICATIONS, 2016, 52 (34) : 5868 - 5871
[7] A new design strategy for organic optoelectronic materials by lateral boryl substitution
Elbing, Mark
Bazan, Guillermo C.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (05) : 834 - 838
[8] Influence of N-Heterocyclic Carbene Steric Bulk on Selectivity in Nickel Catalyzed C-H Bond Silylation, Germylation, and Stannylation
Elsby, Matthew R.
Liu, Junyang
Zhu, Sha
Hu, Lingfei
Huang, Genping
Johnson, Samuel A.
[J]. ORGANOMETALLICS, 2019, 38 (02) : 436 - 450
[9] Nickel-Catalyzed C-H Silylation of Arenes with Vinylsilanes: Rapid and Reversible β-Si Elimination
Elsby, Matthew R.
Johnson, Samuel A.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (27) : 9401 - 9407
[10] Pincer Ruthenium Catalyzed Intramolecular Silylation of C(sp2)-H Bonds
Fang, Huaquan
He, Qiaoxing
Liu, Guixia
Huang, Zheng
[J]. SYNLETT, 2017, 28 (18) : 2468 - 2472

← 1 2 3 4 5 6 7 8 →