A Superamphiphobic Macroporous Silicone Monolith with Marshmallow-like Flexibility

被引：132

作者：

Hayase, Gen ^{[1
]}

Kanamori, Kazuyoshi ^{[1
]}

Hasegawa, George ^{[2
]}

Maeno, Ayaka ^{[3
]}

Kaji, Hironori ^{[3
]}

Nakanishi, Kazuki ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Nishikyo Ku, Kyoto 6158510, Japan

[3] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 41期

关键词：

click chemistry; gels; hydrophobic effect; organic-inorganic hybrid composites; sol-gel processes; SUPEROLEOPHOBIC SURFACES; FTIR;

D O I：

10.1002/anie.201304169

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A monolithic material has marshmallow-like flexibility and superamphiphobic properties on any cutting surface. The two-step synthesis consists of a simple sol-gel process to obtain vinyl-modified superhydrophobic monolithic gels and grafting of perfluoroalkyl groups onto the pore surface to decrease surface energy. These superamphiphobic materials float on water and even on organic liquids with low polarity, such as alkanes. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10788 / 10791

页数：4

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