Reversible photoluminescence switch: A stair-step Cu4I4 coordination polymer based on a dithioether ligand

被引：15
作者：
Kim, Tae Ho [1 ,2 ]
Lee, Sangjin [1 ,2 ]
Jeon, Youngeun [1 ,2 ]
Shin, Yong Woon [3 ]
Kim, Jineun [1 ,2 ]
机构：
[1] Gyeongsang Natl Univ, Dept Chem BK21, Chinju 660701, South Korea
[2] Gyeongsang Natl Univ, Res Inst Nat Sci, Chinju 660701, South Korea
[3] Korea Food & Drug Adm, Test & Analyt Lab, Pusan 608829, South Korea
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 33卷
关键词：
Copper(I) iodide; Luminescence switch; Coordination polymer; Dithioether ligand; VOC; TO-CRYSTAL TRANSFORMATION; COPPER(I) COMPLEXES; ENVIRONMENTAL SENSORS; STRUCTURAL EVIDENCE; LUMINESCENCE; PHOSPHORESCENCE; NETWORKS; SERIES;
D O I：
10.1016/j.inoche.2013.04.018
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A two-dimensional network stair-step Cu4I4 coordination polymer (1) based on 1,4-bis((methylthio) propanoyl)piperazine was prepared. No emission was observed from 1 (off state), while a heated sample (2) of 1 emitted a strong green light (on state). Conversion between 1 and 2 was reversible upon removal of acetonitrile or exposure of 2 to acetonitrile. (c) 2013 The Authors. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：114 / 117
页数：4
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