Synthesis of novel molecular clips based on diethoxycarbonyl glycoluril

被引：37

作者：

Yin, GD ^{[1
]}

Wang, ZG

Chen, YF

Wu, AX

Pan, YJ

机构：

[1] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China

[2] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

来源：

SYNLETT | 2006年 / 01期

关键词：

molecular clips; diethoxycarbonyl glycoluril; aromatic amines; synthetic receptors; conformers;

D O I：

10.1055/s-2005-922761

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel class of molecular clips was synthesized I which are soluble in most non-polar organic solvents. Aromatic amines and diethoxycarbonyl glycoluril were used for the first time in this type of reaction. All reaction products gave satisfying H-1 NMR, C-13 NMR, MS, and IR spectra. In addition, the structure and conformation of 4d were confirmed by single crystal X-ray diffraction.

引用

页码：49 / 52

页数：4

共 31 条

[1] CHEMISTRY OF SYNTHETIC RECEPTORS AND FUNCTIONAL-GROUP ARRAYS .10. ORDERLY FUNCTIONAL-GROUP DYADS - RECOGNITION OF BIOTIN AND ADENINE-DERIVATIVES BY A NEW SYNTHETIC HOST
ADRIAN, JC
WILCOX, CS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (20) : 8055 - 8057
[2] Preparation of glycoluril monomers for expanded cucurbit[n]uril synthesis
Burnett, CA
Lagona, J
Wu, AX
Shaw, JA
Coady, D
Fettinger, JC
Day, AI
Isaacs, L
[J]. TETRAHEDRON, 2003, 59 (11) : 1961 - 1970
[3] MOLECULAR TWEEZERS - SIMPLE-MODEL OF BIFUNCTIONAL INTERCALATION
CHEN, CW
WHITLOCK, HW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (15) : 4921 - 4922
[4] Diederich F., 1991, CYCLOPHANES
[5] MOLECULAR RECOGNITION - BIS-ACYLGUANIDINIUMS PROVIDE A SIMPLE FAMILY OF RECEPTORS FOR PHOSPHODIESTERS
DIXON, RP
GEIB, SJ
HAMILTON, AD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (01) : 365 - 366
[6] Chiral molecular tweezers
Harmata, M
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2004, 37 (11) : 862 - 873
[7] Molecular clips based on propanediurea. Exceptionally high binding affinities for resorcinol guests
Jansen, RJ
de Gelder, R
Rowan, AE
Scheeren, HW
Nolte, RJM
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (08) : 2643 - 2653
[8] Molecular tweezers and clips as synthetic receptors.: Molecular recognition and dynamics in receptor-substrate complexes
Klärner, FG
Kahlert, B
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2003, 36 (12) : 919 - 932
[9] Synthesis and supramolecular properties of trimethylene-bridged clips
Klärner, FG
Lobert, M
Naatz, U
Bandmann, H
Boese, R
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (20) : 5036 - 5047
[10] Cucurbit[n]uril analogues
Lagona, J
Fettinger, JC
Isaacs, L
[J]. ORGANIC LETTERS, 2003, 5 (20) : 3745 - 3747

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