3D Graphitic Foams Derived from Chloroaluminate Anion Intercalation for Ultrafast Aluminum-Ion Battery

被引:323
作者
Wu, Yingpeng [1 ]
Gong, Ming [1 ]
Lin, Meng-Chang [1 ,2 ]
Yuan, Chunze [1 ]
Angell, Michael [1 ]
Huang, Lu [1 ]
Wang, Di-Yan [3 ]
Zhang, Xiaodong
Yang, Jiang [1 ]
Hwang, Bing-Joe [4 ]
Dai, Hongjie [1 ]
机构
[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA
[2] Shandong Univ Sci & Technol, Coll Elect Engn & Automat, Qingdao 266590, Peoples R China
[3] Tunghai Univ, Dept Chem, Taichung 40704, Taiwan
[4] Natl Taiwan Univ Sci & Technol, Dept Chem Engn, Taipei 106, Taiwan
关键词
GRAPHENE OXIDE; PAPER;
D O I
10.1002/adma.201602958
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A 3D graphitic foam vertically aligned graphitic structure and a low density of defects is derived through chloroaluminate anion intercalation of graphite followed by thermal expansion and electrochemical hydrogen evolution. Such aligned graphitic structure affords excellent Al-ion battery characteristics with a discharge capacity of approximate to 60 mA h g(-1) under a high charge and discharge current density of 12 000 mA g(-1) over approximate to 4000 cycles.
引用
收藏
页码:9218 / +
页数:6
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