Microwave versus conventional sintering: Microstructure and mechanical properties of Al2O3-SiC ceramic composites

In this report, Al2O3-SiC ceramic composites were produced at 1500 degrees C by conventional and microwave sintering. For preparing samples, Al2O3 with the second phase x wt.% SiC (x=5, 10, 15, 20) were milled for 180 min. The milled powders were compacted in uniaxial press at 60 MPa for 30 s and sintered by both the conventional and microwave sintering methods. After sintering, densification, grain size, hardness, fracture toughness, phase variation and microstructure of the samples were examined, and comparisons were made for both the sintering methods. The experimental results revealed that there was an increase in density in the microwave sintering method when compared to conventional sintering. However, it was found that the density decreased in both the conventional and microwave sintering methods when there was an increase in SiC content. The highest relative density of 99.7% was obtained in 5 wt. % SiC composite produced by microwave sintering. With regard to hardness and fracture toughness, in both the microwave and conventional sintering methods, though they increased initially and they decreased when there was an increase in SiC content. The maximum hardness and fracture toughness of 24.6 GPa and 5.7 MPa min, respectively, was obtained in 10 wt. % SiC composite sintered by microwave sintering. In both the sintering processes, X-ray diffraction pattern shows the formation of a SiO2 phase in all four compositions along with Al2O3 and SiC phases in conventional sintering, but in microwave sintering only negligible amount of SiO2 phase formed in 15 and 20 wt.% SiC composites. The crystalline size decreases in microwave sintering than conventional sintering due to shorter sintering time. Uniform agglomeration and fine grains in the range of 2-3.6 mu m were formed in microwave sintering, whereas grain size decreases with an increase in the SiC content due to grain boundary pinning due to the intergranular SiC particle. (C) 2018 SECV. Published by Elsevier Espana, S.L.U.