Construction of a supported Ru complex on bifunctional MOF-253 for photocatalytic CO2 reduction under visible light

被引：178

作者：

Sun, Dengrong ^{[1
]}

Gao, Yanhong ^{[1
]}

Fu, Jinlong ^{[1
]}

Zeng, Xianchong ^{[2
]}

Chen, Zhongning ^{[2
]}

Li, Zhaohui ^{[1
]}

机构：

[1] Fuzhou Univ, Res Inst Photocatalysis, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 13期

关键词：

METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE; ARYL HALIDES; OXIDATION; LIGAND; PHOTOREDUCTION; CATALYSTS; INSERTION;

D O I：

10.1039/c4cc09797a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A MOF-253 supported active Ru carbonyl complex (MOF-253-Ru(CO)(2)Cl-2) was constructed for photocatalytic CO2 reduction under visible light irradiation. Its performance can be further improved by immobilization as a photosensitizer. This study highlights the great potential of using MOFs as a solid ligand and platform for the assembly of a complicated catalytic system.

引用

页码：2645 / 2648

页数：4

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