Synthesis of 2-amino-3-fluoroacrylic acid containing peptides

被引：19

作者：

Zhou, H ^{[1
]}

van der Donk, WA ^{[1
]}

机构：

[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 04期

关键词：

D O I：

10.1021/ol006997s

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Peptides containing (E)- and (Z)-3-fluorodehydroalanine have been prepared from serine via a fluoro Pummerer rearrangement. The resulting electrophilic moieties may be useful affinity labels for the identification of the targets of dehydroamino acid containing natural products that act by covalent mechanisms.

引用

页码：593 / 596

页数：4

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