Crystal and molecular structure of 1,2-dimethoxyethane crystallized on a new diffractometer

被引:15
作者
Yokoyama, Y [1 ]
Uekusa, H [1 ]
Ohasi, Y [1 ]
机构
[1] TOKYO INST TECHNOL, FAC SCI, DEPT CHEM, MEGURO KU, TOKYO 152, JAPAN
关键词
D O I
10.1246/cl.1996.443
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Crystal and molecular structure of 1,2-dimethoxyethane (DME) with low melting point (-58 degrees C) was investigated by crystallization on a new imaging plate-Weissenberg type diffractometer with a new low temperature equipment. The crystal belongs to the monoclinic system and the space group is C2/c. There are four molecules in a unit cell. The DME molecule lies on a two-fold axis and has a TGT conformation in. the crystalline state.
引用
收藏
页码:443 / 444
页数:2
相关论文
共 5 条
[1]   A POSSIBLE CRYSTAL-STRUCTURE OF 1,2-DIMETHOXYETHANE - PREDICTION BASED ON A LATTICE VARIABLE MOLECULAR-DYNAMICS [J].
ARIKAWA, T ;
TAJIMA, N ;
TSUZUKI, S ;
TANABE, K ;
HIRANO, T .
JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 1995, 339 :115-124
[2]  
BOESE R, 1994, CORRELATION TRANSFOR
[3]   VIBRATION-SPECTRA AND ROTATIONAL-ISOMERISM OF CHAIN MOLECULES .5. 2,5-DIOXAHEXANE, 2,5-DITHIAHEXANE, AND 2-OXA-5-THIAHEXANE [J].
OGAWA, Y ;
OHTA, M ;
SAKAKIBARA, M ;
MATSUURA, H ;
HARADA, I ;
SHIMANOUCHI, T .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1977, 50 (03) :650-660
[4]  
OHASHI Y, 1995, J MOL STRUCT, V374, P37
[5]  
SHELDRICK GM, 1993, SHELXL93 PROGRAM REF