Deactivation of frits for use in capillary high-performance liquid chromatography and capillary electrochromatography with characterization by imaging with laser-induced fluorescence

被引：30
作者：
Behnke, B
Johansson, J
Zhang, SG
Bayer, E
Nilsson, S
机构：
[1] Univ Tubingen, Dept Organ Chem, D-72076 Tubingen, Germany
[2] Univ Lund, Lund Inst Technol, Dept Phys, S-22100 Lund, Sweden
[3] Univ Lund, Ctr Chem, Dept Tech Analyt Chem, S-22100 Lund, Sweden
来源：
JOURNAL OF CHROMATOGRAPHY A | 1998年 / 818卷 / 02期
关键词：
frits; silica frits; capillary columns;
D O I：
10.1016/S0021-9673(98)00564-0
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
Residual adsorptive activity of frits prepared by sintering silica gel particles used in capillary HPLC and electrochromatography can be significantly reduced by silanization. The adsorption of polar analytes on frits consisting of sintered normal-phase or reversed-phase silica gel before and after deactivation has been characterized by imaging with laser-induced fluorescence in combination with a charge coupled device camera. (C) 1998 Elsevier Science BN. All rights reserved.
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收藏
页码：257 / 259
页数：3
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