Production of trilobite Rydberg molecule dimers with kilo-Debye permanent electric dipole moments

被引：129

作者：

Booth, D. ^{[1
]}

Rittenhouse, S. T. ^{[2
]}

Yang, J. ^{[1
]}

Sadeghpour, H. R. ^{[3
]}

Shaffer, J. P. ^{[1
]}

机构：

[1] Univ Oklahoma, Homer L Dodge Dept Phys & Astron, Norman, OK 73019 USA

[2] Western Washington Univ, Dept Phys & Astron, Bellingham, WA 98225 USA

[3] Harvard Smithsonian Ctr Astrophys, Inst Theoret Atom & Mol Phys, Cambridge, MA 02138 USA

来源：

SCIENCE | 2015年 / 348卷 / 6230期

基金：

美国国家科学基金会;

关键词：

COLLISIONS; STATES;

D O I：

10.1126/science.1260722

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Permanent electric dipole moments are important for understanding symmetry breaking in molecular physics, control of chemical reactions, and realization of strongly correlated many-body quantum systems. However, large molecular permanent electric dipole moments are challenging to realize experimentally. We report the observation of ultralong-range Rydberg molecules with bond lengths of similar to 100 nanometers and kilo-Debye permanent electric dipole moments that form when an ultracold ground-state cesium (Cs) atom becomes bound within the electronic cloud of an extended Cs electronic orbit. The electronic character of this hybrid class of "trilobite" molecules is dominated by degenerate Rydberg manifolds, making them difficult to produce by conventional photoassociation. We used detailed coupled-channel calculations to reproduce their properties quantitatively. Our findings may lead to progress in ultracold chemistry and strongly correlated many-body physics.

引用

页码：99 / 102

页数：4

共 23 条

[1] Photoassociation of Long-Range nD Rydberg Molecules
Anderson, D. A.
Miller, S. A.
Raithel, G.
[J]. PHYSICAL REVIEW LETTERS, 2014, 112 (16)
[2] ABSENCE OF DIFFUSION IN CERTAIN RANDOM LATTICES
ANDERSON, PW
[J]. PHYSICAL REVIEW, 1958, 109 (05): : 1492 - 1505
[3] 3Se and 1Se scattering lengths for e- plus Rb, Cs and Fr collisions
Bahrim, C
Thumm, U
Fabrikant, II
[J]. JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2001, 34 (06) : L195 - L201
[4] Coupling a single electron to a Bose-Einstein condensate
Balewski, Jonathan B.
Krupp, Alexander T.
Gaj, Anita
Peter, David
Buechler, Hans Peter
Loew, Robert
Hofferberth, Sebastian
Pfau, Tilman
[J]. NATURE, 2013, 502 (7473) : 664 - 667
[5] Excitation of Weakly Bound Molecules to Trilobitelike Rydberg States
Bellos, M. A.
Carollo, R.
Banerjee, J.
Eyler, E. E.
Gould, P. L.
Stwalley, W. C.
[J]. PHYSICAL REVIEW LETTERS, 2013, 111 (05)
[6] Observation of ultralong-range Rydberg molecules
Bendkowsky, Vera
Butscher, Bjoern
Nipper, Johannes
Shaffer, James P.
Loew, Robert
Pfau, Tilman
[J]. NATURE, 2009, 458 (7241) : 1005 - U76
[7] Quasiclassical calculations of blackbody-radiation-induced depopulation rates and effective lifetimes of Rydberg nS, nP, and nD alkali-metal atoms with n≤80
Beterov, I. I.
Ryabtsev, I. I.
Tretyakov, D. B.
Entin, V. M.
[J]. PHYSICAL REVIEW A, 2009, 79 (05):
[8] Cold and ultracold molecules: science, technology and applications
Carr, Lincoln D.
DeMille, David
Krems, Roman V.
Ye, Jun
[J]. NEW JOURNAL OF PHYSICS, 2009, 11
[9] PHOTOIONIZATION FROM OUTER ATOMIC SUBSHELLS - MODEL STUDY
COOPER, JW
[J]. PHYSICAL REVIEW, 1962, 128 (02): : 681 - &
[10] Fermi E, 1934, NUOVO CIMENTO, V11, P157, DOI [10.1007/BF02959829, DOI 10.1007/BF02959829]

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