Supramolecular self-assembly of Ph2Tl(S2COMe) based on a rare coordination mode of the xanthate ligand and thallium•••π-phenyl interactions

被引：11

作者：

Casas, JS

Castiñeiras, A

Haiduc, I

Sánchez, A

Semeniuc, RF

Sordo, J

机构：

[1] Univ Babes Bolyai, Fac Chim, RO-3400 Cluj Napoca, Romania

[2] Univ Santiago de Compostela, Fac Farm, Dept Quim Inorgan, E-15706 Santiago De Compostela, Galicia, Spain

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2003年 / 656卷 / 1-3期

关键词：

supramolecular; self-assembly; crystal structure; diphenylthallium; xanthate; thallium center dot center dot center dot pi-aryl interactions; secondary bonds;

D O I：

10.1016/S0022-2860(03)00344-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Diphenylthallium(Ell) xanthates, Ph2TI(S2COR), R = Me, Et, iso-Pr, Bz, have been prepared from Ph2TlBr and KS2COR, and the crystal structure of Ph2Tl(S2COMe) has been determined by single crystal X-ray diffraction. The compound displays a supramolecular structure consisting of Ph(2)T1(S2COMe) tectons, self-assembled through intermolecular T1 (. . .) S and T1... 0 secondary bonds and T1(. . .)pi-phenyl interactions. (C) 2003 Published by Elsevier B.V.

引用

页码：225 / 230

页数：6

共 29 条

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