A strategy for the photoisomerization of aromatic norbornadienes in aqueous media, based on β-cyclodextrin inclusion complexes

被引：0

作者：

Maafi, M ^{[1
]}

Aaron, JJ ^{[1
]}

Lion, C ^{[1
]}

机构：

[1] Univ Paris 07, Inst Topol & Dynam Syst, CNRS, URA 34, F-75005 Paris, France

来源：

PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES | 1998年 / 110卷 / 03期

关键词：

norbornadiene derivatives; inclusion complexes; beta-cyclodextrin; photoisomerization; spectrofluorimetry; spectrophotometry; kinetics;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The formation of 1:1 inclusion complexes between norbornadiene aromatic derivatives and beta-cyclodextrin was investigated spectrofluorometrically, in aqueous media. Photophysical properties, thermodynamic constants, and photoisomerization kinetics of these complexes were determined.

引用

页码：319 / 323

页数：5

共 18 条

[1] CIS REVERSIBLE TRANS PHOTOISOMERIZATION OF AZOBENZENE CYCLODEXTRIN INCLUSION COMPLEXES [J].

BORTOLUS, P ;

MONTI, S .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (19) :5046-5050

[2]

Connors K. A., 1987, BINDING CONSTANTS ME

[3]

FROMMING KH, 1994, TOPICS INCLUSION SCI

[4] USE OF FUNCTIONALIZED POLYMERS AS PHOTOSENSITIZERS IN AN ENERGY-STORAGE REACTION [J].

HAUTALA, RR ;

LITTLE, J ;

SWEET, E .

SOLAR ENERGY, 1977, 19 (05) :503-508

[5] INCLUSION-ENHANCED OPTICAL YIELD AND E/Z RATIO IN ENANTIODIFFERENTIATING PHOTOISOMERIZATION OF CYCLOOCTENE INCLUDED AND SENSITIZED BY BETA-CYDODEXTRIN MONOBENZOATE [J].

INOUE, Y ;

DONG, F ;

YAMAMOTO, K ;

TONG, LH ;

TSUNEISHI, H ;

HAKUSHI, T ;

TAI, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (44) :11033-11034

[6] Effect of the formation of inclusion complexes with β-cyclodextrin on the photoisomerization and fluorescence properties of aromatic norbornadiene derivatives [J].

Maafi, M ;

Aaron, JJ ;

Lion, C .

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1998, 30 (03) :227-241

[7]

Maafi M, 1996, NEW J CHEM, V20, P559

[8] Photochemically induced fluorescence investigation of a beta-cyclodextrin:Azure A inclusion complex and determination of analytical parameters [J].

Maafi, M ;

Laassis, B ;

Aaron, JJ ;

Mahedero, MC ;

DelaPena, AM ;

Salinas, F .

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1995, 22 (03) :235-247

[9] Electrosynthesis and photoisomerization of a new fluorescent aromatic polymer bearing a pendant substituted norbornadiene group [J].

Maafi, M ;

Lion, C ;

Aaron, JJ .

SYNTHETIC METALS, 1996, 83 (02) :167-169

[10] DEVELOPMENT OF A SOLAR-ENERGY STORAGE PROCESS - PHOTOISOMERIZATION OF A NORBORNADIENE DERIVATIVE TO A QUADRICYCLANE DERIVATIVE IN AN AQUEOUS ALKALINE-SOLUTION [J].

MARUYAMA, K ;

TAMIAKI, H ;

KAWABATA, S .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (24) :4742-4749

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