Preparation of CuInSe2 film with electrodeposition

被引:0
作者
Li, WY [1 ]
Yu, J [1 ]
Yu, XB [1 ]
Chen, QL [1 ]
Cai, X [1 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, Minist Educ High Temp Mat & Testing, Open Lab, Shanghai 200030, Peoples R China
来源
FOURTH INTERNATIONAL CONFERENCE ON THIN FILM PHYSICS AND APPLICATIONS | 2000年 / 4086卷
关键词
CuInSe2; electrodeposition; thin film;
D O I
10.1117/12.408435
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
CuInSe2(CIS) films directly electrodeposited on sputtered Mo-glass, sprayed SnO2-glass substrates had been accomplished at room temperature in the potentionstatic mode from a bath containing CuCl, InCl3. 4H(2)O and SeO2. The acidity of bath was adjusted to 1PH. Energy dispersive spectrometry (EDS), Atomic force microscopy (AFM), x-ray diffraction (XRD) and hot-probe method was utilized to characterize the CIS films. The key factor for preparing single-phase CuInSe2 is the proportion of CuCl, InCl3. 4H(2)O and SeO2. The CIS films are nearly stoichiometry of CuInSe2 and polycrystalline on Mo-glass. The Cu excess films are p-type semiconducter, and the In excess films n-type. The deposition potential obviously affects the surface morphology of CIS films. AFM results had indicated that the CIS films on Mo-glass grow in layer and on SnO2 glass in island.
引用
收藏
页码:217 / 220
页数:4
相关论文
共 3 条
[1]   SiO2 sol-gel-coated conducting substrates for CuInSe2 electrodeposition [J].
Guillén, C ;
Gandía, JJ ;
Morales, A ;
Herrero, J .
SURFACE & COATINGS TECHNOLOGY, 1999, 115 (01) :45-51
[2]   Conduction studies on copper indium diselenide thin films [J].
Senthil, K ;
Nataraj, D ;
Prabakar, K ;
Mangalaraj, D ;
Narayandass, SK ;
Udhayakumar, N ;
Krishnakumar, N .
MATERIALS CHEMISTRY AND PHYSICS, 1999, 58 (03) :221-226
[3]   Electrodeposition of CuInSe2 thin films in a glycine acid medium [J].
Ugarte, R ;
Schrebler, R ;
Córdova, R ;
Dalchiele, EA ;
Gómez, H .
THIN SOLID FILMS, 1999, 340 (1-2) :117-124