High performance graphene-based foam fabricated by a facile approach for oil absorption

被引:86
作者
Ji, Cuihong [1 ]
Zhang, Ke [3 ]
Li, Le [2 ]
Chen, Xiaoxia [2 ]
Hu, Jinlong [4 ]
Yan, Deyue [2 ]
Xiao, Guyu [2 ]
He, Xiaohua [1 ]
机构
[1] East China Normal Univ, Sch Chem & Mol Engn, Dept Chem, 500 Dongchuan Rd, Shanghai 200241, Peoples R China
[2] Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Sch Chem & Chem Engn, 800 Dongchuan Rd, Shanghai 200240, Peoples R China
[3] Univ Shanghai Sci & Technol, Sch Mat Sci & Engn, 516 Jungong Rd, Shanghai 200093, Peoples R China
[4] Hunan Univ, Coll Chem & Chem Engn, 2 South Lushan Rd, Changsha 410082, Hunan, Peoples R China
基金
中国国家自然科学基金;
关键词
SELF-ASSEMBLY PROCESS; SUPERHYDROPHOBIC GRAPHENE; OIL/WATER SEPARATION; THERMAL REDUCTION; ORGANIC-SOLVENTS; SPONGY GRAPHENE; CARBON NANOTUBE; FIRE-RESISTANT; AEROGELS; OXIDE;
D O I
10.1039/c7ta02613g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Superhydrophobicity and high elasticity are the two key properties of oil-absorption porous materials. The hydrophobic graphene/carbon black coating on the skeleton of a melamine sponge facilitated the surface to form the micro/nanoscale roughness. The resulting sponge thus was superhydrophobic. Moreover, it inherited the extremely high elasticity of raw melamine sponge, which showed no plastic deformation even after 1000 compression/relaxing cycles. To our knowledge, this was the first superhydrophobic graphene-based porous monolith with such a high elasticity. Its absorbed oils could be recycled by simple squeezing and it was also regenerated by squeezing because of the high elasticity. In addition, it showed a high absorption capacity for common oil contaminations and its fabrication was facile. Therefore, it is really an excellent absorbent for the practical absorption of oil contaminations from water.
引用
收藏
页码:11263 / 11270
页数:8
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