Tuning the selectivity of ruthenium nanoscale catalysts with functionalised ionic liquids: Hydrogenation of nitriles

被引：61

作者：

Prechtl, Martin H. G. ^{[1
]}

Scholten, Jackson D. ^{[1
]}

Dupont, Jairton ^{[1
]}

机构：

[1] Univ Fed Rio Grande do Sul, Lab Mol Chem, Inst Chem, BR-91501970 Porto Alegre, RS, Brazil

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2009年 / 313卷 / 1-2期

关键词：

Ru catalysts; Ru nanoparticles; Ionic liquids; Hydrogenation; Nitrile; Arenes; ARENE HYDROGENATION; PRIMARY AMINES; HECK REACTION; RANEY-CO; NANOPARTICLES; REDUCTION;

D O I：

10.1016/j.molcata.2009.08.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ruthenium nanoparticles prepared in nitrile-functionalised ionic liquids (ILs) display unusual selectivities toward the hydrogenation of nitrile containing aromatic compounds. In particular, a selective catalytic hydrogenative coupling of nitriles was observed. In this transformation, nitrile groups are exclusively hydrogenated in the presence of arenes, which are typically hydrogenated by ruthenium nanoparticles in non-functionalised ILs. The catalyst material was characterised by means of TEM and EDS analysis. Furthermore, molecular species formed during the catalytic process were characterised by MS-analysis of the gaseous phase and the ionic liquid phase by ESI/MS Q-TOR. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：74 / 78

页数：5

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