Hydrodeoxygenation of 2-furyl methyl ketone as a model compound of algal Saccharina Japonica bio-oil using iron phosphide catalyst

被引：21

作者：

Ly, Hoang Vu ^{[1
]}

Galiwango, Emmanuel ^{[1
]}

Kim, Seung-Soo ^{[1
]}

Kim, Jinsoo ^{[2
]}

Choi, Jae Hyung ^{[3
]}

Woo, Hee Chul ^{[3
]}

Othman, Mohd Roslee ^{[4
]}

机构：

[1] Kangwon Natl Univ, Dept Chem Engn, 346 Joongang Ro, Samcheok 25913, Gangwon Do, South Korea

[2] Kyung Hee Univ, Dept Chem Engn, 1732 Deogyeong Daero, Yongin 17104, South Korea

[3] Pukyong Natl Univ, Dept Chem Engn, 365 Sinseon Ro, Busan 48547, South Korea

[4] Univ Sains Malaysia, Sch Chem Engn, Nibong Tebal 14300, Penang, Malaysia

来源：

CHEMICAL ENGINEERING JOURNAL | 2017年 / 317卷

关键词：

Hydrodeoxygenation; Metal phosphide catalyst; 2-Furyl methyl ketone; Bio-oil upgrading; Incipient wetness; SILICA-SUPPORTED MOLYBDENUM; PYROLYSIS OIL; HYDRODESULFURIZATION; METAL; GUAIACOL; CARBON; ACID;

D O I：

10.1016/j.cej.2017.02.080

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

We report the hydrodeoxygenation of 2-furyl methyl ketone over iron phosphide catalyst to reform the C-6 structure into C-7 compounds with higher octane ratings. High conversion and yield were achievable from the reaction at 400 degrees C when 5 wt% Fe2P/gamma-Al2O3 catalyst calcined at 600 degrees C was used. High calcination temperature and reaction temperature are the favorable conditions to achieve high conversion in the reaction. The highest conversion of 92.60% was achieved with 2-allyl furan yield of 79.34% and methyl cylcohexane yield of 13.26% in the liquid phase and 100% carbon dioxide in the gas phase. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：302 / 308

页数：7

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