Polyaniline/multi-walled carbon nanotubes filled biopolymer based flexible substrate electrodes for supercapacitor applications

被引:36
作者
Aswathy, N. R. [1 ]
Kumar, S. Arun [1 ]
Mohanty, S. [1 ]
Nayak, S. K. [1 ]
Palai, Akshaya K. [1 ]
机构
[1] Cent Inst Petrochem Engn & Technol CIPET, Sch Adv Res Polymers, Bhubaneswar 751024, Odisha, India
关键词
Biopolymer blend; Green mixed matrix membrane; Flexible porous substrate; Sustainable electrode material; Supercapacitor; PAPER SUPERCAPACITOR; ENERGY-STORAGE; CELLULOSE; FILM; COMPOSITES; OXIDE;
D O I
10.1016/j.est.2021.102256
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Implementation of green energy storage system via integrating natural materials has become an indispensable requirement for a sustainable future. In this study, polyaniline (PANI) and multiwalled carbon nanotubes (MWCNT) filled flexible porous mixed matrix membrane (MMM) were developed from chitosan (CS) and cellulose acetate (CA) for supercapacitor applications. The results reflect that the unique membrane morphology of the MMM electrode aid for the better areal capacitance of 30.69 mF/cm(2) at a scan rate of 25 mV/s when compared with CA/CS (CC) paper based electrode having same compositions of PANI and MWCNT (15.71 mF/cm(2) at a scan rate of 25 mV/s). The present strategy paved way to biopolymer based mixed matrix membrane (MMM) having facile fabrication, high porosity and flexibility as sustainable electrode materials for energy storage applications.
引用
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页数:10
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共 40 条
[1]   Fabrication of cellulose acetate-chitosan based flexible 3D scaffold-like porous membrane for supercapacitor applications with PVA gel electrolyte [J].
Aswathy, N. R. ;
Palai, Akshaya Kumar ;
Ramadoss, Ananthakumar ;
Mohanty, S. ;
Nayak, S. K. .
CELLULOSE, 2020, 27 (07) :3871-3887
[2]   Freestanding electrically conducting flexible membranes based on novel chitosan/PANI/rGO nanocomposites [J].
Aswathy, N. R. ;
Palai, Akshaya K. ;
Mohanty, S. ;
Nayak, S. K. .
MATERIALS LETTERS, 2020, 259
[3]   Low cost, catalyst free, high performance supercapacitors based on porous nano carbon derived from agriculture waste [J].
Bhat, Vinay S. ;
Kanagavalli, Pandiyaraj ;
Sriram, Ganesan ;
Prabhu, Ramya B. ;
John, Neena S. ;
Veerapandian, Murugan ;
Kurkuri, Mahaveer ;
Hegde, Gurumurthy .
JOURNAL OF ENERGY STORAGE, 2020, 32
[4]   Development of PANI/MWCNTs decorated with cobalt oxide nanoparticles towards multiple electrochemical, photocatalytic and biomedical application sites [J].
Bushra, Rani ;
Arfin, Tanvir ;
Oves, Mohammad ;
Raza, Waseem ;
Mohammad, Faruq ;
Khan, Meraj Alam ;
Ahmad, Anees ;
Azam, Ameer ;
Muneer, Mohammad .
NEW JOURNAL OF CHEMISTRY, 2016, 40 (11) :9448-9459
[5]   CuO@NiO/Polyaniline/MWCNT Nanocomposite as High-Performance Electrode for Supercapacitor [J].
Chakraborty, Ishita ;
Chakrabarty, Nilanjan ;
Senapati, Asim ;
Chakraborty, Amit K. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2018, 122 (48) :27180-27190
[6]   Fe-Al-Mn@chitosan based metal oxides blended cellulose acetate mixed matrix membrane for fluoride decontamination from water: Removal mechanisms and antibacterial behavior [J].
Chaudhary, Mohit ;
Maiti, Abhijit .
JOURNAL OF MEMBRANE SCIENCE, 2020, 611
[7]   Synthesis of polymer composite based on polyaniline-acetylene black-copper ferrite for supercapacitor electrodes [J].
Das, Tapas ;
Verma, Bhawna .
POLYMER, 2019, 168 :61-69
[8]   Effect of waste cellulose fibres on the charge storage capacity of polypyrrole and graphene/polypyrrole electrodes for supercapacitor application [J].
De Adhikari, A. ;
Oraon, R. ;
Tiwari, S. K. ;
Lee, Joong Hee ;
Nayak, G. C. .
RSC ADVANCES, 2015, 5 (35) :27347-27355
[9]   Renewable low cost green functional mesoporous electrodes from Solanum lycopersicum leaves for supercapacitors [J].
Divya, P. ;
Rajalakshmi, R. .
JOURNAL OF ENERGY STORAGE, 2020, 27
[10]   Flexible free-standing polyaniline/graphene/carbon nanotube plastic films with enhanced electrochemical activity for an all-solid-state flexible supercapacitor device [J].
Faraji, Masoud ;
Aydisheh, Hossein Mohammadzadeh .
NEW JOURNAL OF CHEMISTRY, 2019, 43 (11) :4539-4546