Photooxygenation of furans in water and ionic liquid solutions

被引：21

作者：

Astarita, Anna ^{[1
]}

Cermola, Flavio ^{[1
]}

DellaGreca, Marina ^{[1
]}

Iesce, Maria Rosaria ^{[1
]}

Previtera, Lucio ^{[1
]}

Rubino, Maria ^{[1
]}

机构：

[1] Complesso Univ Monte St Angelo, Dipartimento Chim Organ & Biochim, I-80126 Naples, Italy

来源：

GREEN CHEMISTRY | 2009年 / 11卷 / 12期

关键词：

DYE-SENSITIZED PHOTOOXYGENATION; SIMPLE GENERAL-METHOD; PHOTOSENSITIZED OXIDATION; SINGLET OXYGEN; CONVERSION;

D O I：

10.1039/b914726h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photooxygenation of differently functionalized furans is investigated in aqueous solutions and in ionic liquids [emim]Br and [bmim]BF4. The reaction is generally selective and the final products derive from rearrangement of the intermediate endoperoxides, depending mainly on the polarity and/or nucleophilic nature of the solvent.

引用

页码：2030 / 2033

页数：4

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