Topological modulation of the porous structure of a coordination polymer constructed from a flexible building block via framework-guest interaction during self-assembly

被引：6
作者：
Masuya-Suzuki, Atsuko [1 ]
Matsubara, Nozomi [1 ]
Karashimada, Ryunosuke [1 ]
Hoshino, Hitoshi [1 ]
Iki, Nobuhiko [1 ]
机构：
[1] Tohoku Univ, Grad Sch Environm Studies, Aoba Ku, 6-6-07 Aramakiaza Aoba, Sendai, Miyagi 9808579, Japan
来源：
CRYSTENGCOMM | 2016年 / 18卷 / 06期
关键词：
METAL-ORGANIC FRAMEWORKS; AMINE PHENOL LIGANDS; HEPTADENTATE LIGANDS; LANTHANIDE COMPLEXES; GAS-ADSORPTION; CO2; ADSORPTION; FLEXIBILITY; SEPARATION; LUMINESCENCE; MOLECULES;
D O I：
10.1039/c5ce01804h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The porous structure of a coordination polymer constructed from a Sm(III) ion and a conformationally flexible ligand is modulated by guest solvent molecules. The coordination polymer containing the guest DMF molecule possesses isolated hydrophobic and hydrophilic voids, while the one containing the guest methanol molecule has a microchannel with alternately arranged hydrophobic-hydrophilic surfaces.
引用
收藏
页码：872 / 876
页数：5
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