Recent progress in the thermal and catalytic conversion of lignin

被引:165
作者
Ha, Jeong-Myeong [1 ,2 ]
Hwang, Kyung-Ran [3 ]
Kim, Young-Min [4 ]
Jae, Jungho [5 ]
Kim, Kwang Ho [1 ]
Lee, Hyung Won [6 ]
Kim, Jae-Young [7 ]
Park, Young-Kwon [6 ]
机构
[1] Korea Inst Sci & Technol, Clean Energy Res Ctr, Seoul 02792, South Korea
[2] Korea Univ Sci & Technol, KIST Sch, Div Energy & Environm Technol, Seoul 02792, South Korea
[3] Korea Inst Energy Res, Biomass & Waste Energy Lab, Daejeon 34129, South Korea
[4] Daegu Univ, Dept Environm Engn, Gyongsan 02504, South Korea
[5] Pusan Natl Univ, Sch Chem & Biomol Engn, Busan 46241, South Korea
[6] Univ Seoul, Sch Environm Engn, Seoul 02504, South Korea
[7] Natl Inst Forest Sci, Forest Prod Dept, Div Wood Chem, 57 Hoegiro, Seoul 02455, South Korea
基金
新加坡国家研究基金会;
关键词
Lignin; Thermochemical conversion; Catalytic pyrolysis; Catalytic depolymerization; Catalytic oxidation; Aromatic chemicals; VAPOR-PHASE HYDRODEOXYGENATION; O BOND-CLEAVAGE; FAST PYROLYSIS; IONIC-LIQUID; KRAFT LIGNIN; ORGANOSOLV LIGNIN; BIO-OIL; MODEL-COMPOUND; IN-SITU; ENZYMATIC-HYDROLYSIS;
D O I
10.1016/j.rser.2019.05.034
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The issues over increases in energy demand and environmental pollution attributed to excessive use of fossil fuel have been the driving forces of the exploration for eco-friendly resource. Lignocellulosic biomass consisting of carbohydrates and lignin can be a renewable feedstock for replacing fossil fuels in the future because it is a plentiful and carbon neutral material. Especially, lignin, cross-linked phenolic polymers, is a topic of interest owing to its abundant production from pulp/paper industries as well as lignocellulose based biorefinery. The large potential of platform chemicals and biofuels from lignin has opened up an extensive range of opportunities to develop thermal and catalytic conversion technology. Over a few decades, several lignin conversion processes including catalytic pyrolysis, catalytic depolymerization, and catalytic oxidation have been developed to improve target products yields and to suppress side reactions. More recently, lignin-first approaches which maintain carbohydrates intact by selective extraction of lignin as valuable phenolics from whole biomass has been suggested. This review introduces recent ten years progress on thermal and catalytic conversion technology in terms of process type, catalyst development, and target products. This review is expected to offer an influential information for future research into the thermal and catalytic conversion of lignin as well as lignocellulosic feedstock.
引用
收藏
页码:422 / 441
页数:20
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