Adsorption studies of zinc ions on barium titanate from aqueous solution

被引：13

作者：

Guin, R ^{[1
]}

Das, SK ^{[1
]}

Saha, SK ^{[1
]}

机构：

[1] Bhabha Atom Res Ctr, Ctr Variable Energy Cyclotron, Radiochem Lab, Kolkata 700064, W Bengal, India

来源：

RADIOCHIMICA ACTA | 2002年 / 90卷 / 01期

关键词：

adsorption; Zn-65; tracer; barium titanate; kinetics; activation energy; Freundlich isotherm;

D O I：

10.1524/ract.2002.90.1_2002.53

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Adsorption of Zn(II) ions on barium titanate has been studied as a function of concentration of Zn(II) (1.0 x 10(-5)-5.0 x 10(-7) M), temperature (281-313 K) and pH (4-8) of the adsorptive solution using Zn-65 tracer and gamma-ray spectroscopy. The adsorption process was found to obey the first order rate law and the Freundlich adsorption isotherm for the range of concentration studied. The uptake increases from 32 to 70% with the increase in dilution (from 1.0 x 10(-5) to 5.0 x 10(-7) M). The extent of adsorption also increases with increasing temperature and pH of solution. The activation energy for the process was determined to be 12.3 kJ mol(-1). The removal of Zn(II) ions by barium titanate appears to be endothermic and irreversible.

引用

页码：53 / 56

页数：4

共 50 条

[31] Synthesis of platy potassium magnesium titanate and its application in removal of copper ions from aqueous solution
Tan, Yan-ni
Song, Ni
Liu, Yong
Luo, Tao
Dou, Yu-hai
Zhang, Qing
Liu, Qian-nan
Luo, Lan-lan
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2015, 25 (03) : 981 - 990
[32] Adsorption of mercury ions from synthetic aqueous solution using polydopamine decorated SWCNTs
Ghasemi, Seyedeh Sima
Hadavifar, Mojtaba
Maleki, Behrooz
Mohammadnia, Esmail
JOURNAL OF WATER PROCESS ENGINEERING, 2019, 32
[33] Adsorption of U (VI) ions from aqueous solution using silicon dioxide nanopowder
Mahmoud, Mohamed Ahmed
JOURNAL OF SAUDI CHEMICAL SOCIETY, 2018, 22 (02) : 229 - 238
[34] Adsorption of manganese ions from aqueous solution by using manganese oxide coated zeolite
Rahman, Md Wasikur
Ong, Huei Ruey
Kong, Wendy Yin Jou
Abdullah, Hamidah
Khan, Md Maksudur Rahman
DESALINATION AND WATER TREATMENT, 2021, 224 : 273 - 281
[35] Equilibrium and kinetics studies for the adsorption of Ni2+ and Fe3+ ions from aqueous solution by graphene oxide
Konicki, Wojciech
Aleksandrzak, Malgorzata
Mijowska, Ewa
POLISH JOURNAL OF CHEMICAL TECHNOLOGY, 2017, 19 (03) : 120 - 129
[36] Zinc adsorption from aqueous solution on biosorbent from urban pruning waste
Sia, Gustavo Bordon
Vernasqui, Lais Gimenes
Consolin-Filho, Nelson
Goncalves, Morgana Suszek
da Silva Medeiros, Flavia Vieira
ENVIRONMENTAL TECHNOLOGY, 2022, 43 (05) : 728 - 736
[37] Study of adsorption of zinc ions on hydrous zirconium oxide surface
Das, SK
Guin, R
Saha, SK
RADIOCHIMICA ACTA, 2000, 88 (02) : 107 - 110
[38] Experimental Studies on the Removal of Aluminium Ions from Synthetic Aqueous Solution by Hydroxyapatites
Humelnicu, Doina
Zinicovscaia, Inga
Humelnicu, Ionel
Ignat, Maria
ACTA CHIMICA SLOVENICA, 2021, 68 (04) : 821 - 832
[39] Zinc and copper adsorption from an aqueous solution onto activated carbon
Kuecuekguel, Enver Yaser
Kudu, Selin
FRESENIUS ENVIRONMENTAL BULLETIN, 2006, 15 (06): : 512 - 517
[40] Adsorption of copper(II) and zinc(II) ions from aqueous solution by activated carbon derived from halophytes (Suaeda maritime)
El-Bouraie, Mohamed M.
Mohamed, Gehad G.
DESALINATION AND WATER TREATMENT, 2017, 94 : 198 - 210

← 1 2 3 4 5 →