Acyl anion free N-heterocyclic carbene organocatalysis

被引：718
作者：
Ryan, Sarah J. [1 ]
Candish, Lisa [1 ]
Lupton, David W. [1 ]
机构：
[1] Monash Univ, Clayton, Vic 3800, Australia
来源：
CHEMICAL SOCIETY REVIEWS | 2013年 / 42卷 / 12期
关键词：
HIGHLY ENANTIOSELECTIVE SYNTHESIS; CATALYTIC-ACTIVITY; 4+2 CYCLOADDITION; 1ST EXAMPLE; KETENES; UMPOLUNG; ESTERS; MECHANISM; ALCOHOLS; ENONES;
D O I：
10.1039/c3cs35522e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction discovery using N-heterocyclic carbene organocatalysis has been dominated by the chemistry of acyl anion equivalents. Recent studies demonstrate that NHCs are far more diverse catalysts, with a variety of reactions discovered that proceed without acyl anion equivalent formation. In this tutorial review selected examples of acyl anion free NHC catalysis using carbonyl compounds are presented.
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页码：4906 / 4917
页数：12
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