C-meso-(3,5,7,7,10,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) nickel(II) bis(thiocyanate)

被引：5

作者：

Curtis, NF

Pawley, R

Robinson, WT

机构：

[1] Victoria Univ Wellington, Sch Chem & Phys Sci, Wellington, New Zealand

[2] Univ Canterbury, Dept Chem, Christchurch 1, New Zealand

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷

关键词：

D O I：

10.1107/S160053680504078X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title complex, (1RS, 3SR, 8SR, 10RS-3,5,7,7,10,12,12,14-octamethyl- 1,4,8,11-tetraazacyclotetradeca-4,11-diene-kappa N-4(1,4,8,11))-nickel(II) bis(thiocyanate), [Ni(C18H36N4)](NCS)(2), has a centrosymmetrical square-planar singlet ground state nickel(II) cation, with Ni-N-amine = 1.940 (1) angstrom and Ni-N-imine = 1.921 (1) angstrom. The C-3 methyl substituent is axially oriented. The thiocyanate N atom is hydrogen bonded to the NH group.

引用

页码：M80 / M82

页数：3

共 13 条

[11] Crystal structure and spectroscopic properties of a new five-coordinate mixed-ligand nickel(II) complex with a macrocyclic ligand:: [Ni(trans[14]diene)SCN]ClO4 (trans[14]diene=5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) [J].