The structure of the [Fe(CN)(6)](4-) shallow electron centre in silver chloride

被引：15
作者：
Bennebroek, MT [1 ]
Schmidt, J [1 ]
Eachus, RS [1 ]
Olm, MT [1 ]
机构：
[1] EASTMAN KODAK CO,IMAGING RES & ADV DEV,ROCHESTER,NY 14650
来源：
JOURNAL OF PHYSICS-CONDENSED MATTER | 1997年 / 9卷 / 15期
关键词：
D O I：
10.1088/0953-8984/9/15/014
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
The results of an ENDOR study of electrons shallowly trapped at [Fe(CN)(6)](4-) complexes doped in AgCl emulsions reveal that the dopant replaces a [AgCl6](5-) lattice unit without an additional lowering of the local symmetry and without the association of charge-compensating cationic vacancies. Effects of the grain structure seem to interfere in the interpretation of the results from C-13-enriched [Fe(CN)(6)](4-)-doped emulsions, for which an ensemble of slightly different electron centres is believed to be observed.
引用
收藏
页码：3227 / 3240
页数：14
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