The structure of the [Fe(CN)(6)](4-) shallow electron centre in silver chloride

被引：15

作者：

Bennebroek, MT ^{[1
]}

Schmidt, J ^{[1
]}

Eachus, RS ^{[1
]}

Olm, MT ^{[1
]}

机构：

[1] EASTMAN KODAK CO,IMAGING RES & ADV DEV,ROCHESTER,NY 14650

来源：

JOURNAL OF PHYSICS-CONDENSED MATTER | 1997年 / 9卷 / 15期

关键词：

D O I：

10.1088/0953-8984/9/15/014

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

The results of an ENDOR study of electrons shallowly trapped at [Fe(CN)(6)](4-) complexes doped in AgCl emulsions reveal that the dopant replaces a [AgCl6](5-) lattice unit without an additional lowering of the local symmetry and without the association of charge-compensating cationic vacancies. Effects of the grain structure seem to interfere in the interpretation of the results from C-13-enriched [Fe(CN)(6)](4-)-doped emulsions, for which an ensemble of slightly different electron centres is believed to be observed.

引用

页码：3227 / 3240

页数：14

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