Transformations of n-hexane and cyclohexane by barrier discharge processing in inert gases

被引：7

作者：

Kudryashov, SV ^{[1
]}

Ryabov, AY ^{[1
]}

Sirotkina, EE ^{[1
]}

Shchegoleva, GS ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Petr Chem, Siberian Div, Tomsk 634055, Russia

来源：

HIGH ENERGY CHEMISTRY | 2001年 / 35卷 / 02期

关键词：

Physical Chemistry; Energy Consumption; Hydrocarbon; Cyclohexane; Discharge Processing;

D O I：

10.1023/A:1004125607204

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The conversion of n-hexane and cyclohexane by barrier discharge treatment in He, Ar, Kr, or Xe was studied. The action of a barrier discharge on n-hexane vapor primarily results in the formation of branched-chain hydrocarbons (93.48 wt %). Bicyclohexyl is the main reaction product of cyclohexane; alkyl and alkenyl substituted cyclohexanes (48.12 wt %) are also formed. Using n-hexane as an example, it was demonstrated that the energy consumption increased from 1.30 to 2.17 keV per hydrocarbon molecule converted in the following order of inert gases: He, Ar, Kr, and Xe.

引用

页码：120 / 122

页数：3